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Aldehydes, Ketones and Carboxylic Acids · Question 33

JEE Main 2025 (Online) 2nd April Morning ShiftMCQEasy📈 Topic in 32% papers+4−1
1

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Statement I is correct but Statement II is incorrect
  2. Both Statement I and Statement II are correct
  3. Both Statement I and Statement II are incorrect
  4. Statement I is incorrect but Statement II is correct

Answer

(1) Statement I is correct but Statement II is incorrect

Solution

Vanillin is 4-hydroxy-3-methoxybenzaldehyde: it has a phenolic –OH and an aromatic –CHO group.

Statement I: phenolic –OH is acidic ArOH + NaOH ArO-Na+ + H2O.

The –CHO group is oxidised by Tollens' reagent silver mirror (RCHO RCOO-, Ag+ Ag). Statement I is correct.

Statement II: aldol condensation needs at least one α-hydrogen.

In vanillin the –CHO carbon is attached directly to the benzene ring no α-hydrogen no self aldol condensation. Statement II is incorrect.

Answer: (1)

JEE Main 2025 (Online) 2nd April Morning Shift

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2

Consider the following molecules: [figure] The correct order of rate of hydrolysis is :

  1. p > q > r > s
  2. r > q > p > s
  3. p > r > q > s
  4. q > p > r > s
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3

Consider the following reactions. From these reactions which reaction will give carboxylic acid as a major product? Choose the correct answer from the options given below:

  1. A, B and E only
  2. A and D only
  3. B, C and E only
  4. B and E only
JEE Main 2025 (Online) 2nd April Evening Shift
4

The product (P) formed in the following reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
JEE Main 2025 (Online) 29th January Morning Shift
5

[figure] 0.1 mole of compound 'S' will weigh g. (Given molar mass in g mol-1 C : 12, H : 1, O : 16)

JEE Main 2025 (Online) 29th January Morning Shift
6

Both acetaldehyde and acetone (individually) undergo which of the following reactions? Choose the correct answer from the options given below:

  1. C and E Only
  2. A, B and D Only
  3. A, C and E Only
  4. B, C and D Only
JEE Main 2025 (Online) 28th January Morning Shift
7

The compounds that produce CO2 with aqueous NaHCO3 solution are: Choose the correct answer from the options given below:

  1. A and C Only
  2. A, B and E Only
  3. A and B Only
  4. A, C and D Only
JEE Main 2025 (Online) 28th January Morning Shift
8

The total number of compounds from below when treated with hot KMnO4, giving benzoic acid is: [figure] , [figure] , [figure] , [figure] , [figure] , [figure] , [figure] , [figure]

  1. 4
  2. 3
  3. 5
  4. 6
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All JEE Main Chemistry chapters
Physical ChemistrySome Basic Concepts of ChemistryStructure of AtomStates of MatterThermodynamicsEquilibriumRedox ReactionsSolutionsElectrochemistryChemical Kinetics
Inorganic ChemistryClassification of Elements and Periodicity in PropertiesChemical Bonding and Molecular Structurep-Block Elements (Group 13 & 14)p-Block Elements (Group 15–18)d- and f-Block ElementsCoordination Compounds
Organic ChemistryOrganic Chemistry – Some Basic Principles and TechniquesIsomerismHydrocarbonsHaloalkanes and HaloarenesAlcohols, Phenols and EthersAldehydes, Ketones and Carboxylic AcidsAminesBiomoleculesPrinciples Related to Practical Chemistry