Match List I with List II :
- A-I, B-III, C-II, D-IV
- A-II, B-IV, C-III, D-I
- A-III, B-I, C-IV, D-II
- A-III, B-I, C-II, D-IV
Answer
(3) A-III, B-I, C-IV, D-II
Solution
A. [Pt(NH3)2Cl2]: square planar [MA2B2] type ⇒ cis and trans forms ⇒ geometrical isomerism (III)
B. [Co(en)3]3+: three didentate ligands ⇒ non-superimposable mirror images (d and l) ⇒ optical isomerism (I)
C. [Co(NH3)5NO2]Cl2: ambidentate NO2- binds through N (nitrito-N) or O (nitrito-O) ⇒ linkage isomerism (IV)
D. [Cr(H2O)6]Cl3: water inside or outside the coordination sphere, e.g. [Cr(H2O)5Cl]Cl2 H2O ⇒ solvate (hydrate) isomerism (II)
∴ A-III, B-I, C-IV, D-II
Answer: (3)