Fluorine is a stronger oxidising agent than chlorine because : Choose the most appropriate answer from the options given :
- B and C only
- A and B only
- A and C only
- A and D only
Answer
(2) A and B only
Solution
As per NCERT, the oxidising power of halogens depends on bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy:
12X2(g) X(g) X-(g) X-(aq)
Although the electron gain enthalpy of fluorine is less negative than that of chlorine, F is the stronger oxidising agent because of the low enthalpy of dissociation of the F–F bond (A) and the high hydration enthalpy of F- (B).
Statement C is true but works against fluorine, so it is not a reason; D is not the reason given.
A and B only
Answer: (2)