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p-Block Elements (Group 15–18) · Question 20

NEET (UG) 2019MCQMedium📈 Topic in 50% papers+4−1
1

The correct structure of tribromooctaoxide is :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(4) [figure]

Solution

Tribromooctaoxide (Br3O8) is a neutral molecule, so its structure cannot carry any negative charge ⇒ options (1), (2) and (3) are rejected.

Its structure is O3Br-BrO2-BrO3: each terminal Br is joined to three O atoms and the central Br to two O atoms, all through Br=O bonds.

Oxidation states: terminal Br = +6, central Br = +4 ⇒ average 2(+6) + 43 = + 163 (= 2 83, consistent with Br3O8).

Answer: (4)

NEET (UG) 2019

Keep practising — p-Block Elements (Group 15–18)

2

Which is the correct thermal stability order for H2E (E = O, S, Se, Te and Po)?

  1. H2Po < H2Te < H2Se < H2S < H2O
  2. H2Se < H2Te < H2Po < H2O < H2S
  3. H2S < H2O < H2Se < H2Te < H2Po
  4. H2O < H2S < H2Se < H2Te < H2Po
NEET (UG) 2019
3

Match the following : Which of the following is the correct option?

  1. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
  2. (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
  3. (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
  4. (a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
NEET (UG) 2019
4

Identify the incorrect statement related to PCl5 from the following :

  1. Axial P–Cl bonds are longer than equatorial P–Cl bonds
  2. PCl5 molecule is non-reactive
  3. Three equatorial P–Cl bonds make an angle of 120° with each other
  4. Two axial P–Cl bonds make an angle of 180° with each other
NEET (UG) 2019
5

Match the Xenon compounds in Column-I with its structure in Column-II and assign the correct code :

  1. (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
  2. (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
  3. (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
  4. (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
NEET (UG) 2019
6

Which of the following statements is not true for halogens?

  1. All are oxidizing agents.
  2. All form monobasic oxyacids.
  3. All but fluorine show positive oxidation states.
  4. Chlorine has the highest electron-gain enthalpy.
NEET 2018
7

Match the interhalogen compounds of column-I with the geometry in column-II and assign the correct code.

  1. (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
  2. (a)-(v), (b)-(iv), (c)-(iii), (d)-(ii)
  3. (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
  4. (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
NEET 2017
8

In which pair of ions both the species contain S-S bond?

  1. S4O62-, S2O32-
  2. S2O72-, S2O82-
  3. S4O62-, S2O72-
  4. S2O72-, S2O32-
NEET 2017
9

Name the gas that can readily decolourise acidified KMnO4 solution.

  1. SO2
  2. NO2
  3. P2O5
  4. CO2
NEET 2017
10

HgCl2 and I2 both when dissolved in water containing I- ions, the pair of species formed is

  1. HgI2, I-
  2. HgI42-, I3-
  3. Hg2I2, I-
  4. HgI2, I3-
NEET 2017
11

Match the compounds given in column I with the hybridisation and shape given in column II and mark the correct option

  1. (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
  2. (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
  3. (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
  4. (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
NEET 2016 (Phase 1)

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