Among the following options, the correct trend in the electron gain enthalpy is
- I > Br > Cl > F
- F > Cl > Br > I
- Br > Cl > F > I
- Cl > F > Br > I
Answer
(4) Cl > F > Br > I
Solution
Chlorine has a more negative electron gain enthalpy than fluorine due to the smaller size and high interelectronic repulsions in the compact 2p-subshell of fluorine.
The magnitude of negative electron gain enthalpy for halogens follows the order:
Cl > F > Br > I
Answer: (4)