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Aldehydes, Ketones and Carboxylic Acids · Question 18

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1

Match List-I with List-II. Choose the correct answer from the options given below

  1. (a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)
  2. (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)
  3. (a) - (i), (b) - (iii), (c) - (ii), (d) - (iv)
  4. (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)

Answer

(4) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)

Solution

(a) Cyanohydrin: >C=O + HCN >C(OH)CN ⇒ (iv)

(b) Acetal: carbonyl compound + alcohol (dry HCl) ⇒ (iii)

(c) Schiff's base (substituted imine): >C=O + RNH2 >C=N-R + H2O ⇒ (ii)

(d) Oxime: >C=O + NH2OH >C=N-OH + H2O ⇒ (i)

∴ (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)

Answer: (4)

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2

Which one of the following is not formed when acetone reacts with 2-pentanone in the presence of dilute NaOH followed by heating?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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3

Which of the following reactions is not an example for nucleophilic addition-elimination reaction?

  1. CH3CHO + NH3 CH3CH=NH + H2O
  2. CH3CHO + NaHSO3 CH3- H | OH |C-SO3Na
  3. CH3CHO + NH2OH CH3CH=N-OH + H2O
  4. CH3CHO + C6H5NHNH2 CH3CH=N-NHC6H5 + H2O
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4

The product formed from the following reaction sequence is [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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5

The products A and B in the following reaction sequence are : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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6

The incorrect method to synthesize benzaldehyde is

  1. [figure] , CH3MgBr, followed by H3O+
  2. [figure] , H2, Pd-BaSO4
  3. [figure] , DIBAL-H, followed by H2O
  4. [figure] , CrO2Cl2 in CS2, followed by H3O+
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7

Match List-I with List-II Choose the correct answer from the options given below.

  1. (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
  2. (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
  3. (a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)
  4. (a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
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8

The intermediate compound 'X' in the following chemical reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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9

The product formed in the following chemical reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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10

Identify compound X in the following sequence of reactions : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
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11

Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is known as :

  1. Cannizzaro's reaction
  2. Cross Cannizzaro's reaction
  3. Cross Aldol condensation
  4. Aldol condensation
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