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Aldehydes, Ketones and Carboxylic Acids · Question 25

NEET (UG) 2021MCQEasy📈 Topic in 50% papers+4−1
1

The intermediate compound 'X' in the following chemical reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]

Answer

(1) [figure]

Solution

As per NCERT (Etard reaction), chromyl chloride oxidises the methyl group of toluene to a chromium complex, which on hydrolysis gives benzaldehyde.

C6H5CH3 + CrO2Cl2 CS2 C6H5CH(OCrOHCl2)2 (chromium complex, X)

C6H5CH(OCrOHCl2)2 H3O+ C6H5CHO

∴ X = C6H5CH(OCrOHCl2)2

Answer: (1)

NEET (UG) 2021

Keep practising — Aldehydes, Ketones and Carboxylic Acids

2

The product formed in the following chemical reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
NEET (UG) 2021
3

Identify compound X in the following sequence of reactions : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
NEET (UG) 2020
4

Reaction between benzaldehyde and acetophenone in presence of dilute NaOH is known as :

  1. Cannizzaro's reaction
  2. Cross Cannizzaro's reaction
  3. Cross Aldol condensation
  4. Aldol condensation
NEET (UG) 2020
5

The major product of the following reaction is : [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
NEET (UG) 2019
6

Compound A, C8H10O, is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow precipitate with characteristic smell. A and Y are respectively

  1. [figure] and I2
  2. [figure] and I2
  3. [figure] and I2
  4. [figure] and I2
NEET 2018
7

Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their

  1. formation of intramolecular H-bonding
  2. formation of carboxylate ion
  3. more extensive association of carboxylic acid via van der Waals' forces of attraction
  4. formation of intermolecular H-bonding
NEET 2018
8

Of the following, which is the product formed when cyclohexanone undergoes aldol condensation followed by heating?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
NEET 2017
9

Consider the reactions, [figure] Identify A, X, Y and Z.

  1. A-Methoxymethane, X-Ethanol, Y-Ethanoic acid, Z-Semicarbazide.
  2. A-Ethanal, X-Ethanol, Y-But-2-enal, Z-Semicarbazone.
  3. A-Ethanol, X-Acetaldehyde, Y-Butanone, Z-Hydrazone.
  4. A-Methoxymethane, X-Ethanoic acid, Y-Acetate ion, Z-Hydrazine.
NEET 2017
10

Which of the following reagents would distinguish cis-cyclopentane-1,2-diol from the trans-isomer?

  1. MnO2
  2. Aluminium isopropoxide
  3. Acetone
  4. Ozone
NEET 2016 (Phase 1)
11

The product formed by the reaction of an aldehyde with a primary amine is

  1. carboxylic acid
  2. aromatic acid
  3. Schiff's base
  4. ketone
NEET 2016 (Phase 1)

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