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Coordination Compounds

JEE Main 2024 (Online) 4th April Morning ShiftMCQEasy📈 Topic in 54% papers+4−1
Ques. 1JEE Main 2024, 4 April (Morning Shift)

The correct sequence of ligands in the order of decreasing field strength is :

  1. NCS- > EDTA4- > CN- > CO
  2. CO > H2O > F- > S2-
  3. S2- > -OH > EDTA4- > CO
  4. -OH > F- > NH3 > CN-

Answer

(2) CO > H2O > F- > S2-

Solution

Spectrochemical series (increasing field strength):

I- < Br- < SCN- < Cl- < S2- < F- < OH- < C2O42- < H2O < NCS- < EDTA4- < NH3 < en < CN- < CO

(A): CO is the strongest, not the weakest ⇒ wrong

(B): CO > H2O > F- > S2- ⇒ correct

(C): S2- is among the weakest ⇒ wrong

(D): CN- is stronger than NH3, F-, OH- ⇒ wrong

Answer: (2)

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Ques. 2JEE Main 2024, 4 April (Evening Shift)

If an iron (III) complex with the formula [Fe(NH3)x(CN)y]- has no electron in its eg orbital, then the value of x + y is

  1. 6
  2. 4
  3. 3
  4. 5
Ques. 3JEE Main 2024, 4 April (Evening Shift)

The number of unpaired d-electrons in [Co(H2O)6]3+ is .

  1. 0
  2. 2
  3. 1
  4. 4
Ques. 4JEE Main 2024, 1 February (Morning Shift)

Which of the following complex is homoleptic?

  1. [Ni(NH3)2Cl2]
  2. [Co(NH3)4Cl2]+
  3. [Fe(NH3)4Cl2]+
  4. [Ni(CN)4]2-
Ques. 5JEE Main 2024, 1 February (Morning Shift)

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

  1. Statement I is incorrect but Statement II is correct
  2. Both Statement I and Statement II are correct
  3. Both Statement I and Statement II are incorrect
  4. Statement I is correct but Statement II is incorrect
Ques. 6JEE Main 2024, 1 February (Evening Shift)

[Co(NH3)6]3+ and [CoF6]3- are respectively known as :

  1. Inner orbital Complex, Spin paired Complex
  2. Spin paired Complex, Spin free Complex
  3. Spin free Complex, Spin paired Complex
  4. Outer orbital Complex, Inner orbital Complex
Ques. 7JEE Main 2024, 31 January (Morning Shift)

The correct statements from following are: Choose the correct answer from the options given below:

  1. B, C only
  2. B, D only
  3. A, C only
  4. A, D only
Ques. 8JEE Main 2024, 31 January (Morning Shift)

The 'Spin only' Magnetic moment for [Ni(NH3)6]2+ is 10-1 BM. (given = Atomic number of Ni : 28)

Ques. 9JEE Main 2024, 31 January (Evening Shift)

Select the option with correct property -

  1. [Ni(CO)4] and [NiCl4]2- both Paramagnetic
  2. [Ni(CO)4] and [NiCl4]2- both Diamagnetic
  3. [NiCl4]2- Diamagnetic, [Ni(CO)4] Paramagnetic
  4. [Ni(CO)4] Diamagnetic, [NiCl4]2- Paramagnetic
Ques. 10JEE Main 2024, 31 January (Evening Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-IV, B-I, C-II, D-III
  2. A-III, B-II, C-IV, D-I
  3. A-II, B-III, C-IV, D-I
  4. A-IV, B-III, C-I, D-II
Ques. 11JEE Main 2024, 30 January (Morning Shift)

Choose the correct statements from the following : Choose the correct answer from the options given below :

  1. (B), (C), (E) only
  2. (A), (D), (E) only
  3. (C), (D), (E) only
  4. (A), (B), (C) only

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