Given below are two statements : In the light of the above statements, choose the correct answer from the options given below
- Statement I is true but Statement II is false
- Statement I is false but Statement II is true
- Both Statement I and Statement II are true
- Both Statement I and Statement II are false
Answer
(4) Both Statement I and Statement II are false
Solution
Statement I: The H–X bond length increases from HF to HI because the size of X increases. The longest bond is H–I, and iodine has the largest (not the smallest) covalent radius in group 17. Statement I is false.
Statement II: Boiling points: PH3 < AsH3 < NH3 < SbH3 < BiH3
(NH3 is raised by hydrogen bonding) the lowest boiling hydride is PH3 E = P.
As per NCERT, P can expand its covalency beyond 4 using vacant 3d orbitals (e.g. PCl5, [PF6]-); only nitrogen is limited to a maximum covalency of 4.
Statement II is false.
Answer: (4)