A group 15 element forms d - d bond with transition metals. It also forms a hydride, which is the strongest base among the hydrides of other group members that form d - d bond. The atomic number of the element is .
Answer
15
Solution
As per NCERT, phosphorus and arsenic can form d - d bonds with transition metals when their compounds like P(C2H5)3 and As(C6H5)3 act as ligands. Nitrogen cannot (no d orbitals in its valence shell).
Basic strength of group 15 hydrides decreases down the group:
NH3 > PH3 > AsH3 > SbH3 BiH3
Among the elements forming d - d bonds (P, As), the hydride PH3 is the strongest base.
The element is phosphorus, atomic number 15.
Answer: 15