Equilibrium

Consider the following reactions in which all the reactants and products are present in gaseous state 2xy x2 + y2 K1 = 2.5 105 xy + 12z2 xyz K2 = 5 10-3 The value of K3 for the equilibrium 12x2 + 12y2 + 12z2 xyz is :

1. 2.5 10-3
2. 2.5 103
3. 1.0 10-5
4. 5 10-3

Solid carbon, CaO and CaCO3 are mixed and allowed to attain equilibrium at T K. CaCO3(s) CaO(s) + CO2(g) Kp1 = 0.08 atm C(s) + CO2(g) 2CO(g) Kp2 = 2 atm The partial pressure of CO is 10-1 atm

One mole each of He and A(g) are taken in a 10 L closed flask and heated to 400 K to establish the following equilibrium. A(g) B(g) Kc for this reaction at 400 K is 4.0. The partial pressures (in atm) of He and B(g) are respectively (at equilibrium) (Assume He, A(g) and B(g) behave as ideal gases) (Given : R = 0.082 L atm K-1 mol-1)

1. 3.28, 2.624
2. 2.624, 3.28
3. 3.28, 0.656
4. 0.656, 6.56

Given is a concentrated solution of a weak electrolyte AxBy of concentration 'c' and dissociation constant 'K'. The degree of dissociation is given by :

1. [K cx+y-1xxyy ]x+y
2. ( Kcx+y-1xxyy ) 1x+y
3. ( cx+y-1xxyyK )x+y
4. ( cx+y-1xxyyK ) 1x+y

In a closed flask at 600 K, one mole of X2Y4(g) attains equilibrium as given below : X2Y4(g) 2XY2(g) At equilibrium, 75% X2Y4(g) was dissociated and the total pressure is 1 atm. The magnitude of rG (in kJ mol-1) at this temperature is . (Nearest Integer) (Given : R = 8.3 J mol-1 K-1; ln 10 = 2.3, log 2 = 0.3, log 3 = 0.48, log 5 = 0.69, log 7 = 0.84)

M3A2 is a sparingly soluble salt of molar mass y g mol-1 and solubility x g L-1. The ratio of the molar concentration of the anion ( A3-) to the solubility product of the salt is

1. 154 y4x4
2. y5108x4
3. 108 x5y5
4. 1108 y4x4

Arrange the following resultant mixtures in increasing order of their pH values Choose the correct answer from the options given below :

1. B < C < A
2. C < A < B
3. C < B < A
4. A < C < B

The values of pressure equilibrium constant recorded at different temperatures for the following equilibrium reaction have been given below A(g) B(g) + C(g) array|c|c| 1T ( K-1) & 10 Kp \ 0.05 & 3.5 \ 0.06 & 2.5 \ 0.07 & 1.5 \ array The magnitude of H R calculated from the above data is . (Nearest integer)

The reaction A(g) B(g) + C(g) was initiated with the amount 'a' of A(g). At equilibrium it is found that the amount of A(g) remaining is (a − x) at a total pressure of p. The equilibrium constant Kp of the reaction can be calculated from the expression :

1. x2a2 + x2 p
2. x2a2 - x2 p
3. a + x2x2 p
4. a2 - x2x2 p

At T(K), the equilibrium constant of A2(g) + B2(g) C(g) is 2.7 10-5. What is the equilibrium constant for 13A2(g) + 13B2(g) 13C(g) at the same temperature?

1. (2.7 10-5)3
2. 6 10-2
3. 2.7 10-5
4. 3 10-2