Which of the following reactions are disproportionation reactions? Choose the correct answer from the options given below :
- (A), (B)
- (A), (D)
- (B), (C), (D)
- (A), (B), (C)
Answer
(1) (A), (B)
Solution
Disproportionation: the same element (in one oxidation state) is both oxidised and reduced.
(A): Cu +1 → +2 ( Cu2+) and 0 (Cu) ⇒ (A) is disproportionation
(B): Mn +6 → +7 (MnO4-) and +4 (MnO2) ⇒ (B) is disproportionation
(C): Mn +7 → +6, +4 (only reduced); O −2 → 0 (oxidised) ⇒ two different elements ⇒ (C) is not
(D): Mn +7 and Mn +2 → Mn +4 (comproportionation) ⇒ (D) is not
Answer: (1)