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Total number of isomeric compounds (including stereoisomers) formed by monochlorination of 2-methylbutane is .
6
2-Methylbutane: ( aCH3)2 bCH- cCH2- dCH3 ⇒ 4 kinds of H (a, b, c, d) ⇒ 4 structural products
(a) ClCH2- CH(CH3)-CH2CH3: chiral ⇒ 2 (d and l)
(b) (CH3)2CCl-CH2CH3: achiral ⇒ 1
(c) (CH3)2CH- CHCl-CH3: chiral ⇒ 2 (d and l)
(d) (CH3)2CH-CH2-CH2Cl: achiral ⇒ 1
∴ Total = 2 + 1 + 2 + 1 = 6
Answer: 6
Number of geometrical isomers possible for the given structure is/are . [figure]
2-chlorobutane + Cl2 C4H8Cl2 (isomers) Total number of optically active isomers shown by C4H8Cl2, obtained in the above reaction is .
Which one of the following will show geometrical isomerism?
Highest enol content will be shown by:
3-Methylhex-2-ene on reaction with HBr in presence of peroxide forms an addition product (A). The number of possible stereoisomers for 'A' is .
Total number of compounds with Chiral carbon atoms from following is . [figure] CH3-CH2-CH(NO2)-COOH CH3-CH2-CHBr-CH2-CH3 CH3-CH(I)-CH2-NO2 CH3-CH2-CH(OH)-CH2OH CH3- I |CH-CH(I)-C2H5