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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 9th April Morning ShiftNumericalMedium📈 Topic in 29% papers+4
Ques. 1JEE Main 2024, 9 April (Morning Shift)

The total number of species from the following in which one unpaired electron is present, is . N2, O2, C2-, O2-, O22-, H2+, CN-, He2+

Answer

4

Solution

Using MO theory (electrons in brackets):

N2 (14): all paired, 0; CN- (14): 0; O22- (18): 0

O2 (16): 2px1 2py1, so 2 unpaired

C2- (13): 2pz1, 1; O2- (17): 2p3, 1

H2+ (1): 1s1, 1; He2+ (3): 1s1, 1

Hence 4 species (C2-, O2-, H2+, He2+).

Answer: 4

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Ques. 2JEE Main 2024, 9 April (Evening Shift)

The correct increasing order for bond angles among BF3, PF3 and ClF3 is :

  1. BF3 = PF3 < ClF3
  2. BF3 < PF3 < ClF3
  3. ClF3 < PF3 < BF3
  4. PF3 < BF3 < ClF3
Ques. 3JEE Main 2024, 9 April (Evening Shift)

Total number of electrons present in ( ) molecular orbitals of O2, O2+ and O2- is .

Ques. 4JEE Main 2024, 8 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-II, B-IV, C-I, D-III
  2. A-III, B-I, C-IV, D-II
  3. A-IV, B-III, C-I, D-II
  4. A-III, B-IV, C-I, D-II
Ques. 5JEE Main 2024, 8 April (Morning Shift)

Number of molecules from the following which are exceptions to octet rule is . CO2, NO2, H2SO4, BF3, CH4, SiF4, ClO2, PCl5, BeF2, C2H6, CHCl3, CBr4

Ques. 6JEE Main 2024, 8 April (Evening Shift)

When A and B are the wave functions of atomic orbitals, then is represented by :

  1. A + 2 B
  2. A - B
  3. A - 2 B
  4. A + B
Ques. 7JEE Main 2024, 8 April (Evening Shift)

Number of molecules having bond order 2 from the following molecules is . C2, O2, Be2, Li2, Ne2, N2, He2

Ques. 8JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-III, B-II, C-IV, D-I
  2. A-III, B-IV, C-II, D-I
  3. A-II, B-IV, C-III, D-I
  4. A-II, B-III, C-I, D-IV
Ques. 9JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-II, B-III, C-I, D-IV
  2. A-III, B-I, C-II, D-IV
  3. A-IV, B-I, C-III, D-II
  4. A-III, B-IV, C-II, D-I
Ques. 10JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-III, B-I, C-IV, D-II
  2. A-III, B-IV, C-I, D-II
  3. A-IV, B-III, C-I, D-II
  4. A-II, B-I, C-IV, D-III
Ques. 11JEE Main 2024, 6 April (Morning Shift)

Number of molecules from the following which can exhibit hydrogen bonding is . (nearest integer) CH3OH, H2O, C2H6, C6H6, [figure] , HF, NH3

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