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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 9th April Morning ShiftMCQEasy📈 Topic in 22% papers+4−1
Ques. 1JEE Main 2024, 9 April (Morning Shift)

In which one of the following pairs the central atoms exhibit sp2 hybridization ?

  1. BF3 and NO2-
  2. NH2- and BF3
  3. NH2- and H2O
  4. H2O and NO2

Answer

(1) BF3 and NO2-

Solution

Steric number = σ bond pairs + lone pairs on the central atom; 3 means sp2 and 4 means sp3.

BF3: 3 bp + 0 lp = 3, so sp2

NO2-: 2 bp + 1 lp = 3, so sp2

NH2- and H2O: 2 bp + 2 lp = 4, so sp3

Hence only pair (1) has both central atoms sp2; (2), (3) and (4) each contain an sp3 species.

Answer: (1)

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Ques. 2JEE Main 2024, 9 April (Morning Shift)

The total number of species from the following in which one unpaired electron is present, is . N2, O2, C2-, O2-, O22-, H2+, CN-, He2+

Ques. 3JEE Main 2024, 9 April (Evening Shift)

The correct increasing order for bond angles among BF3, PF3 and ClF3 is :

  1. BF3 = PF3 < ClF3
  2. BF3 < PF3 < ClF3
  3. ClF3 < PF3 < BF3
  4. PF3 < BF3 < ClF3
Ques. 4JEE Main 2024, 9 April (Evening Shift)

Total number of electrons present in ( ) molecular orbitals of O2, O2+ and O2- is .

Ques. 5JEE Main 2024, 8 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-II, B-IV, C-I, D-III
  2. A-III, B-I, C-IV, D-II
  3. A-IV, B-III, C-I, D-II
  4. A-III, B-IV, C-I, D-II
Ques. 6JEE Main 2024, 8 April (Morning Shift)

Number of molecules from the following which are exceptions to octet rule is . CO2, NO2, H2SO4, BF3, CH4, SiF4, ClO2, PCl5, BeF2, C2H6, CHCl3, CBr4

Ques. 7JEE Main 2024, 8 April (Evening Shift)

When A and B are the wave functions of atomic orbitals, then is represented by :

  1. A + 2 B
  2. A - B
  3. A - 2 B
  4. A + B
Ques. 8JEE Main 2024, 8 April (Evening Shift)

Number of molecules having bond order 2 from the following molecules is . C2, O2, Be2, Li2, Ne2, N2, He2

Ques. 9JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-III, B-II, C-IV, D-I
  2. A-III, B-IV, C-II, D-I
  3. A-II, B-IV, C-III, D-I
  4. A-II, B-III, C-I, D-IV
Ques. 10JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-II, B-III, C-I, D-IV
  2. A-III, B-I, C-II, D-IV
  3. A-IV, B-I, C-III, D-II
  4. A-III, B-IV, C-II, D-I
Ques. 11JEE Main 2024, 6 April (Morning Shift)

Match List I with List II Choose the correct answer from the options given below:

  1. A-III, B-I, C-IV, D-II
  2. A-III, B-IV, C-I, D-II
  3. A-IV, B-III, C-I, D-II
  4. A-II, B-I, C-IV, D-III

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