Which one of the following structures represents nylon 6, 6 polymer?
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- [figure]
- [figure]
- [figure]
Answer
(4) [figure]
Solution
Nylon 6, 6 is a polyamide prepared by condensation polymerisation of hexamethylenediamine with adipic acid under high pressure and at high temperature:
nHOOC(CH2)4COOH + nH2N(CH2)6NH2
553 K, high pressure - [NH(CH2)6NH-CO(CH2)4CO ]n - + 2nH2O
The repeating unit contains six carbon atoms from the diamine and six carbon atoms from the dicarboxylic acid joined by amide (-CO-NH-) linkages.
In option (4), the unit -CO-(CH2-CH2)2-CO- = -CO(CH2)4CO- comes from adipic acid and -NH-(CH2)6-NH- comes from hexamethylenediamine, joined by amide linkages.
The structures in options (1), (2) and (3) are addition polymers of substituted alkenes with no amide linkage.
Answer: (4)