Arrange the following atomic orbitals of multi electron atoms in order of increasing energy. Choose the correct answer from the options given below:
- C < D < B < A < E
- B < A < E < C < D
- E < C < D < B < A
- E < B < A < D < C
Answer
(4) E < B < A < D < C
Solution
In a multi-electron atom the energy of an orbital is decided by the (n + l) rule: lower (n + l) ⇒ lower energy; for equal (n + l), lower n ⇒ lower energy. (m does not affect the energy.)
A. n = 3, l = 2 ⇒ 3d, n + l = 5
B. n = 4, l = 0 ⇒ 4s, n + l = 4
C. n = 6, l = 1 ⇒ 6p, n + l = 7
D. n = 5, l = 1 ⇒ 5p, n + l = 6
E. n = 2, l = 1 ⇒ 2p, n + l = 3
∴ Increasing energy: 2p < 4s < 3d < 5p < 6p, i.e. E < B < A < D < C
Answer: (4)