Identify the incorrect statement from the following
- Alkali metals react with water to form their hydroxides.
- The oxidation number of K in KO2 is +4.
- Ionisation enthalpy of alkali metals decreases from top to bottom in the group.
- Lithium is the strongest reducing agent among the alkali metals.
Answer
(2) The oxidation number of K in KO2 is +4.
Solution
KO2 is potassium superoxide, made of K+ and O2- ions.
x + 2 (- 12 ) = 0
x = +1
The oxidation number of K is +1, not +4; statement (2) is incorrect.
As per NCERT, alkali metals react with water to form hydroxides and dihydrogen; ionisation enthalpy decreases down the group; and lithium, with the most negative E value, is the strongest reducing agent.
Answer: (2)