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Principles Related to Practical Chemistry · Question 47

JEE Main 2025 (Online) 3rd April Evening ShiftMCQEasy📈 Topic in 65% papers+4−1
1

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at 300 K = 15 mm Hg)

  1. 15.71\%
  2. 17.46\%
  3. 7.85\%
  4. 20.95\%

Answer

(1) 15.71\%

Solution

Pressure of dry nitrogen = observed pressure − aqueous tension

pN2 = 715 - 15 = 700 mm Hg

Volume of dry N2 at STP (273 K, 760 mm Hg):

V0 = p1V1T1 T0p0

= 700 60300 273760

= 50.29 mL

22400 mL of N2 at STP weighs 28 g,

mass of N2 = 28 50.2922400 = 0.0629 g

\% N = 0.06290.4 100

= 15.71\%

Answer: (1)

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2

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

  1. A, D and E only
  2. A, B and C only
  3. B, D and E only
  4. C, D and E only
JEE Main 2025 (Online) 2nd April Morning Shift
3

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

  1. 20.87
  2. 12.57
  3. 1.257
  4. 18.67
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4

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

  1. Sulphide ion
  2. Sulphite ion
  3. Sulphate ion
  4. Sodium ion
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5

Match List-I with List-II. Choose the correct answer from the options given below:

  1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
  4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
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6

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

  1. (B) and (D) Only
  2. (A), (B) and (C) Only
  3. (A) and (B) Only
  4. (A) and (C) Only
JEE Main 2025 (Online) 29th January Morning Shift
7

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
JEE Main 2025 (Online) 28th January Morning Shift
8

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

  1. Cr3+
  2. Ti3+
  3. Ni2+
  4. Mn2+
JEE Main 2025 (Online) 28th January Morning Shift
9

The purification method based on the following physical transformation is : (X)Solid Heat (X)Vapour Cool (X)Solid

  1. Extraction
  2. Crystallization
  3. Distillation
  4. Sublimation
JEE Main 2025 (Online) 28th January Evening Shift
10

Identify the inorganic sulphides that are yellow in colour : Choose the correct answer from the options given below :

  1. (D) and (E) only
  2. (A) and (B) only
  3. (A), (D) and (E) only
  4. (A) and (C) only
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