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Principles Related to Practical Chemistry · Question 48

JEE Main 2025 (Online) 2nd April Morning ShiftMCQEasy📈 Topic in 29% papers+4−1
1

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

  1. A, D and E only
  2. A, B and C only
  3. B, D and E only
  4. C, D and E only

Answer

(2) A, B and C only

Solution

A: 2Cu2+ + [Fe(CN)6]4- Cu2[Fe(CN)6], a chocolate brown precipitate (confirmatory test of Cu2+) correct.

B: 4Fe3+ + 3[Fe(CN)6]4- Fe4[Fe(CN)6]3, Prussian blue precipitate (test of Fe3+) correct.

C: 2Zn2+ + [Fe(CN)6]4- Zn2[Fe(CN)6], white or bluish white precipitate (test of Zn2+) correct.

D: Mg2+ is not tested with potassium ferrocyanide and gives no blue precipitate (it is confirmed with disodium hydrogen phosphate / magneson reagent) incorrect.

E: Ba2+ gives no white precipitate with potassium ferrocyanide (it is confirmed as yellow BaCrO4 with potassium chromate) incorrect.

A, B and C only are correct.

Answer: (2)

JEE Main 2025 (Online) 2nd April Morning Shift

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2

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

  1. 20.87
  2. 12.57
  3. 1.257
  4. 18.67
JEE Main 2025 (Online) 2nd April Evening Shift
3

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

  1. Sulphide ion
  2. Sulphite ion
  3. Sulphate ion
  4. Sodium ion
JEE Main 2025 (Online) 2nd April Evening Shift
4

Match List-I with List-II. Choose the correct answer from the options given below:

  1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
  4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
JEE Main 2025 (Online) 2nd April Evening Shift
5

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

  1. (B) and (D) Only
  2. (A), (B) and (C) Only
  3. (A) and (B) Only
  4. (A) and (C) Only
JEE Main 2025 (Online) 29th January Morning Shift
6

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
JEE Main 2025 (Online) 28th January Morning Shift
7

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

  1. Cr3+
  2. Ti3+
  3. Ni2+
  4. Mn2+
JEE Main 2025 (Online) 28th January Morning Shift
8

The purification method based on the following physical transformation is : (X)Solid Heat (X)Vapour Cool (X)Solid

  1. Extraction
  2. Crystallization
  3. Distillation
  4. Sublimation
JEE Main 2025 (Online) 28th January Evening Shift
9

Identify the inorganic sulphides that are yellow in colour : Choose the correct answer from the options given below :

  1. (D) and (E) only
  2. (A) and (B) only
  3. (A), (D) and (E) only
  4. (A) and (C) only
JEE Main 2025 (Online) 28th January Evening Shift

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