Given below are two statements : In the light of the above statements, choose the correct answer from the options given below
- Statement I is false but Statement II is true
- Both Statement I and Statement II are false
- Statement I is true but Statement II is false
- Both Statement I and Statement II are true
Answer
(4) Both Statement I and Statement II are true
Solution
Statement I: In (X) the two CH3 groups (and the H atoms) eclipse each other, dihedral angle between the CH3 groups = 0 .
maximum torsional and steric strain (X) is the least stable conformer.
In (Y) the two CH3 groups are anti, dihedral angle = 180 .
minimum strain (Y) is the most stable conformer.
Statement I is true.
Statement II: As per NCERT, torsional strain is maximum in the eclipsed form and minimum in the staggered (anti) form. On going from (X) (0 ) to (Y) (180 ) the dihedral angle increases and the strain falls to its minimum (stability: anti > gauche > eclipsed).
Statement II is true.
Answer: (4)