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Haloalkanes and Haloarenes

JEE Main 2024 (Online) 4th April Morning ShiftMCQMedium📈 Topic in 15% papers+4−1
Ques. 1JEE Main 2024, 4 April (Morning Shift)

[figure] Identify B and C and how are A and C related?

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Answer

(1) [figure]

Solution

[figure]

Alc. NaOH ⇒ E2 dehydrobromination of the side chain (aryl C–Br does not react) ⇒ B = 4-bromostyrene

HBr (no peroxide) ⇒ Markovnikov addition: Br goes to the benzylic C ⇒ C = 1-bromo-4-(1-bromoethyl)benzene

A and C: same formula C8H8Br2, same skeleton, side-chain Br on different C ⇒ position isomers

Answer: (1)

Keep practising — Haloalkanes and Haloarenes

Ques. 2JEE Main 2024, 4 April (Morning Shift)

Identify the correct set of reagents or reaction conditions 'X' and 'Y' in the following set of transformation. CH3-CH2-CH2-Br 'X' Product 'Y' CH3- Br |CH-CH3

  1. X = dil.aq. NaOH, 20°C, Y = HBr/ acetic acid
  2. X = conc.alc. NaOH, 80°C, Y = Br2/CHCl3
  3. X = dil.aq. NaOH, 20°C, Y = Br2/CHCl3
  4. X = conc.alc. NaOH, 80°C, Y = HBr/ acetic acid
Ques. 3JEE Main 2024, 4 April (Evening Shift)

[figure] Product P is

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Ques. 4JEE Main 2024, 4 April (Evening Shift)

Find out the major product formed from the following reaction. [Me : –CH3] [figure]

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Ques. 5JEE Main 2024, 1 February (Morning Shift)

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). In the light of the above statements, choose the most appropriate answer from the options given below :

  1. (A) is correct but (R) is not correct
  2. Both (A) and (R) are correct and (R) is the correct explanation of (A)
  3. (A) is not correct but (R) is correct
  4. Both (A) and (R) are correct but (R) is not the correct explanation of (A)
Ques. 6JEE Main 2024, 1 February (Evening Shift)

Match List - I with List - II. Choose the correct answer from the options given below :

  1. (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
  2. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  3. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
  4. (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
Ques. 7JEE Main 2024, 31 January (Morning Shift)

The product (C) in the below mentioned reaction is : CH3-CH2-CH2-Br [ ]KOH(alc) A HBr B [KOH(aq)] C

  1. Propan-1-ol
  2. Propyne
  3. Propan-2-ol
  4. Propene
Ques. 8JEE Main 2024, 31 January (Morning Shift)

[figure] The total number of hydrogen atoms in product A and product B is .

Ques. 9JEE Main 2024, 31 January (Evening Shift)

Identify structure of 2,3-dibromo-1-phenylpentane.

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Ques. 10JEE Main 2024, 31 January (Evening Shift)

Identify A and B in the following reaction sequence. [figure]

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Ques. 11JEE Main 2024, 30 January (Morning Shift)

Example of vinylic halide is :

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