Thermodynamics

Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are -382.64 kJ mol-1 and -145.6 J K-1 mol-1, respectively. Standard Gibbs energy change for the same reaction at 298 K is

1. -221.1 kJ mol-1
2. -339.3 kJ mol-1
3. -439.3 kJ mol-1
4. -523.2 kJ mol-1

Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is

1. Ssystem + Ssurroundings > 0
2. Ssystem - Ssurroundings > 0
3. Ssystem > 0 only
4. Ssurroundings > 0 only

The work done during the expansion of a gas from a volume of 4 dm3 to 6 dm3 against a constant external pressure of 3 atm is (1 L atm = 101.32 J)

1. -6 J
2. -608 J
3. +304 J
4. -304 J

For the reaction, C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(l) at constant temperature, H - E is

1. +RT
2. -3RT
3. +3RT
4. -RT

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm-3, respectively. If the standard free energy difference ( G ) is equal to 1895 J mol-1, the pressure at which graphite will be transformed into diamond at 298 K is

1. 11.14 108 Pa
2. 11.14 107 Pa
3. 11.14 106 Pa
4. 11.14 105 Pa

What is the entropy change (in J K-1 mol-1) when one mole of ice is converted into water at 0 C? (The enthalpy change for the conversion of ice to liquid water is 6.0 kJ mol-1 at 0 C).

1. 20.13
2. 2.013
3. 2.198
4. 21.98

For which one of the following equations is H react equal to H f for the product ?

1. Xe(g) + 2F2(g) XeF4(g)
2. 2CO(g) + O2(g) 2CO2(g)
3. N2(g) + O3(g) N2O3(g)
4. CH4(g) + 2Cl2(g) CH2Cl2(l) + 2HCl(g)

The molar heat capacity of water at constant pressure, C, is 75 J K-1 mol-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is

1. 1.2 K
2. 2.4 K
3. 4.8 K
4. 6.6 K

Unit of entropy is

1. J K-1 mol-1
2. J mol-1
3. J-1 K-1 mol-1
4. J K mol-1

In a closed insulated container a liquid is stirred with a paddle to increase the temperature. Which of the following is true?

1. E = W 0, q = 0
2. E = W = q 0
3. E = 0, W = q 0
4. W = 0, E = q 0

Heat of combustion Ho for C(s), H2(g) and CH4(g) are -94, -68 and -213 kcal/mol, then Ho for C(s) + 2H2(g) CH4(g) is

1. -17 kcal
2. -111 kcal
3. -170 kcal
4. -85 kcal

2 moles of an ideal gas at 27 temperature is expanded reversibly from 2 lit. to 20 lit. Find entropy change. (R = 2 cal/mol K)

1. 92.1
2. 0
3. 4
4. 9.2

Change in enthalpy for reaction, 2H2O2(l) 2H2O(l) + O2(g) if heat of formation of H2O2(l) and H2O(l) are -188 and -286 kJ/mol respectively, is

1. -196 kJ/mol
2. +196 kJ/mol
3. +948 kJ/mol
4. -948 kJ/mol

When 1 mol of gas is heated at constant volume temperature is raised from 298 to 308 K. Heat supplied to the gas is 500 J. Then which statement is correct ?

1. q = w = 500 J, E = 0
2. q = E = 500 J, w = 0
3. q = -w = 500 J, E = 0
4. E = 0, q = w = -500 J

Enthalpy of CH4 + 12O2 CH3OH is negative. If enthalpy of combustion of CH4 and CH3OH are x and y respectively. Then which relation is correct?

1. x > y
2. x < y
3. x = y
4. x ≥ y

2Zn + O2 2ZnO; = -616 J 2Zn + S2 2ZnS; = -293 J S2 + 2O2 2SO2; = -408 J for the following reaction 2ZnS + 3O2 2ZnO + 2SO2 is

1. -731 J
2. -1317 J
3. -501 J
4. +731 J

The entropy change in the fusion of one mole of a solid melting at 27 (latent heat of fusion is 2930 J mol-1) is :

1. 9.77 J/mol-K
2. 10.77 J/mol-K
3. 9.07 J/mol-K
4. 0.977 J/mol-K

For the reaction, C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l) which one is true

1. = - RT
2. = + RT
3. = + 2RT
4. = - 2RT