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Chemical Bonding and Molecular Structure · Question 48

AIPMT 2014MCQEasy📈 Topic in 75% papers+4−1
1

Which one of the following species has plane triangular shape?

  1. N3-
  2. NO3-
  3. NO2-
  4. CO2

Answer

(2) NO3-

Solution

N3- and CO2: 2 σ-bond pairs, no lone pair on central atom ⇒ sp, linear.

NO2-: 2 bond pairs + 1 lone pair on N ⇒ sp2, bent (V-shaped).

NO3-: 3 bond pairs, no lone pair on N ⇒ sp2, plane triangular (trigonal planar).

Answer: (2)

AIPMT 2014

Keep practising — Chemical Bonding and Molecular Structure

2

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-
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3

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4
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4

Which of the following is paramagnetic?

  1. CN-
  2. NO+
  3. CO
  4. O2-
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5

Which one of the following molecules contains no bond?

  1. SO2
  2. NO2
  3. CO2
  4. H2O
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6

The pair of species that has the same bond order in the following is

  1. CO, NO+
  2. NO-, CN-
  3. O2, N2
  4. O2, B2
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7

In which of the following pair both the species have sp3 hybridization ?

  1. SiF4, BeH2
  2. NF3, H2O
  3. NF3, BF3
  4. H2S, BF3
NEET 2013 (Karnataka)
8

In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.

  1. O2 O2+
  2. C2 C2+
  3. NO NO+
  4. N2 N2+
NEET 2013 (Karnataka)
9

During change of O2 to O2- ion, the electron adds on which one of the following orbitals ?

  1. * orbital
  2. orbital
  3. * orbital
  4. orbital
AIPMT 2012 (Mains)
10

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  1. NO < O2- < C22- < He2+
  2. O2- < NO < C22- < He2+
  3. C22- < He2+ < O2- < NO
  4. He2+ < O2- < NO < C22-
AIPMT 2012 (Mains)
11

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?

  1. [BCl3 and BrCl3]
  2. [NH3 and NO3-]
  3. [NF3 and BF3]
  4. [BF4- and NH4+]
AIPMT 2012 (Prelims)

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