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Chemical Bonding and Molecular Structure · Question 58

AIPMT 2012 (Prelims)MCQEasy📈 Topic in 12% papers+4−1
1

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?

  1. [BCl3 and BrCl3]
  2. [NH3 and NO3-]
  3. [NF3 and BF3]
  4. [BF4- and NH4+]

Answer

(4) [BF4- and NH4+]

Solution

(1) BCl3: sp2, trigonal planar; BrCl3: sp3d (3 bp + 2 lp), T-shaped.

(2) NH3: sp3, pyramidal; NO3-: sp2, trigonal planar.

(3) NF3: sp3, pyramidal; BF3: sp2, trigonal planar.

(4) BF4-: 4 bp + 0 lp ⇒ sp3, tetrahedral; NH4+: 4 bp + 0 lp ⇒ sp3, tetrahedral.

∴ BF4- and NH4+ are isostructural.

Answer: (4)

AIPMT 2012 (Prelims)

Keep practising — Chemical Bonding and Molecular Structure

2

Bond order of 1.5 is shown by

  1. O2+
  2. O2-
  3. O22-
  4. O2
AIPMT 2012 (Prelims)
3

Which of the following species contains three bond pairs and one lone pair around the central atom ?

  1. H2O
  2. BF3
  3. NH2-
  4. PCl3
AIPMT 2012 (Prelims)
4

The pair of species with the same bond order is

  1. O22-, B2
  2. O2+, NO+
  3. NO, CO
  4. N2, O2
AIPMT 2012 (Prelims)
5

Which of the following structures is the most preferred and hence of lowest energy for SO3?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2011 (Mains)
6

The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description?

  1. O2-, O22- – Both diamagnetic
  2. O2+, O2 – Both paramagnetic
  3. O, O22- – Both paramagnetic
  4. O+, O22- – Both paramagnetic
AIPMT 2011 (Mains)
7

Which of the following has the minimum bond length ?

  1. O2+
  2. O2-
  3. O22-
  4. O2
AIPMT 2011 (Prelims)
8

Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals, NO2-, NO3-, NH2-, NH4+, SCN-?

  1. NO2- and NO3-
  2. NH4+ and NO3-
  3. SCN- and NH2-
  4. NO2- and NH2-
AIPMT 2011 (Prelims)
9

The correct order of increasing bond length of C-H, C-O, C-C and C=C is

  1. C-H < C=C < C-O < C-C
  2. C-C < C=C < C-O < C-H
  3. C-O < C-H < C-C < C=C
  4. C-H < C-O < C-C < C=C
AIPMT 2011 (Prelims)
10

The pairs of species of oxygen and their magnetic behavior are noted below. Which of the following presents the correct description?

  1. O2-, O22- - Both diamagnetic
  2. O+, O22- - Both paramagnetic
  3. O2+, O2 - Both paramagnetic
  4. O, O22- - Both paramagnetic
AIPMT 2011 (Prelims)
11

Considering the state of hybridization of carbon atoms, find out the molecule among the following which is linear ?

  1. CH3-CH=CH-CH3
  2. CH3-C C-CH3
  3. CH2=CH-CH2-C CH
  4. CH3-CH2-CH2-CH3
AIPMT 2011 (Prelims)

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