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Chemical Bonding and Molecular Structure · Question 49

NEET 2013MCQMedium📈 Topic in 75% papers+4−1
1

XeF2 is isostructural with

  1. SbCl3
  2. BaCl2
  3. TeF2
  4. ICl2-

Answer

(4) ICl2-

Solution

XeF2: 2 bond pairs + 3 lone pairs ⇒ sp3d, linear.

ICl2-: I has 7 + 1 = 8 valence electrons ⇒ 2 bond pairs + 3 lone pairs ⇒ sp3d, linear.

SbCl3: 3 bp + 1 lp ⇒ pyramidal; TeF2: 2 bp + 2 lp ⇒ bent; BaCl2 is an ionic compound.

∴ XeF2 is isostructural with ICl2-.

Answer: (4)

NEET 2013

Keep practising — Chemical Bonding and Molecular Structure

2

Which of the following is a polar molecule?

  1. SiF4
  2. XeF4
  3. BF3
  4. SF4
NEET 2013
3

Which of the following is paramagnetic?

  1. CN-
  2. NO+
  3. CO
  4. O2-
NEET 2013
4

Which one of the following molecules contains no bond?

  1. SO2
  2. NO2
  3. CO2
  4. H2O
NEET 2013
5

The pair of species that has the same bond order in the following is

  1. CO, NO+
  2. NO-, CN-
  3. O2, N2
  4. O2, B2
NEET 2013 (Karnataka)
6

In which of the following pair both the species have sp3 hybridization ?

  1. SiF4, BeH2
  2. NF3, H2O
  3. NF3, BF3
  4. H2S, BF3
NEET 2013 (Karnataka)
7

In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.

  1. O2 O2+
  2. C2 C2+
  3. NO NO+
  4. N2 N2+
NEET 2013 (Karnataka)
8

During change of O2 to O2- ion, the electron adds on which one of the following orbitals ?

  1. * orbital
  2. orbital
  3. * orbital
  4. orbital
AIPMT 2012 (Mains)
9

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them

  1. NO < O2- < C22- < He2+
  2. O2- < NO < C22- < He2+
  3. C22- < He2+ < O2- < NO
  4. He2+ < O2- < NO < C22-
AIPMT 2012 (Mains)
10

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?

  1. [BCl3 and BrCl3]
  2. [NH3 and NO3-]
  3. [NF3 and BF3]
  4. [BF4- and NH4+]
AIPMT 2012 (Prelims)
11

Bond order of 1.5 is shown by

  1. O2+
  2. O2-
  3. O22-
  4. O2
AIPMT 2012 (Prelims)

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