Chemical Bonding and Molecular Structure · Question 23

In SO2, NO2- and N3-, the hybridizations at the central atom are respectively :

1. sp2, sp2 and sp2
2. sp, sp2 and sp
3. sp2, sp and sp
4. sp2, sp2 and sp

Which of the following molecule(s) show/s paramagnetic behavior? Choose the correct answer from the options given below:

1. A & C only
2. A & E Only
3. A & D Only
4. B Only

Given below are two statements: In the light of the above statements, choose the most appropriate answer from the options given below:

1. Both Statement I and Statement II are correct
2. Both Statement I and Statement II are incorrect
3. Statement I is correct but Statement II is incorrect
4. Statement I is incorrect but Statement II is correct

Match the LIST-I with LIST-II Choose the correct answer from the options given below:

1. A-IV, B-I, C-II, D-III
2. A-III, B-I, C-IV, D-II
3. A-II, B-III, C-IV, D-I
4. A-I, B-II, C-III, D-IV

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

1. Both Statement I and Statement II are false
2. Both Statement I and Statement II are true
3. Statement I is false but Statement II is true
4. Statement I is true but Statement II is false

A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:

1. Pentagonal planar
2. Square pyramidal
3. Trigonal bipyramidal
4. Octahedral

Among SO2, NF3, NH3, XeF2, ClF3 and SF4, the hybridization of the molecule with nonzero dipole moment and highest number of lone-pairs of electrons on the central atom is

1. sp3
2. dsp2
3. sp3d2
4. sp3d

Which among the following molecules is (a) involved in sp3d hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom?

1. XeF4
2. XeF2
3. PF5
4. SF4

An element 'E' has the ionisation enthalpy value of 374 kJ mol-1. 'E' reacts with elements A, B, C and D with electron gain enthalpy values of −328, −349, −325 and −295 kJ mol-1, respectively. The correct order of the products EA, EB, EC and ED in terms of ionic character is :

1. EB > EA > EC > ED
2. EA > EB > EC > ED
3. ED > EC > EA > EB
4. ED > EC > EB > EA

The sum of sigma ( ) and pi ( ) bonds in Hex-1,3-dien-5-yne is .