In SO2, NO2- and N3-, the hybridizations at the central atom are respectively :
- sp2, sp2 and sp2
- sp, sp2 and sp
- sp2, sp and sp
- sp2, sp2 and sp
Answer
(4) sp2, sp2 and sp
Solution
Steric number = σ bonds + lone pairs on the central atom.
SO2: S has 2 σ bonds + 1 lone pair = 3 sp2 (bent)
NO2-: N has 2 σ bonds + 1 lone pair = 3 sp2 (bent)
N3- (N- = N+ = N-): central N has 2 σ bonds + 0 lone pair = 2 sp (linear)
sp2, sp2 and sp
Answer: (4)