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Equilibrium · Question 93

AIPMT 2002MCQMedium📈 Topic in 25% papers+4−1
1

Reaction BaO2(s) BaO(s) + O2(g); H = +ve. In equilibrium condition, pressure of O2 depends on

  1. increase mass of BaO2
  2. increase mass of BaO
  3. increase temperature on equilibrium
  4. increase mass of BaO2 and BaO both

Answer

(3) increase temperature on equilibrium

Solution

For this heterogeneous equilibrium, the active masses of the pure solids are taken as constant (unity).

⇒ Kp = pO2

∴ At equilibrium, pO2 is fixed by Kp alone and does not depend on the amounts of BaO2 or BaO.

∵ Kp changes only with temperature, and the reaction is endothermic, increasing the temperature increases Kp and hence pO2.

Answer: (3)

AIPMT 2002

Keep practising — Equilibrium

2

Solubility of MX2 type electrolytes is 0.5 10-4 mole/lit., then find out Ksp of electrolytes.

  1. 5 10-12
  2. 25 10-10
  3. 1 10-13
  4. 5 10-13
AIPMT 2002
3

Which has highest pH?

  1. CH3COOK
  2. Na2CO3
  3. NH4Cl
  4. NaNO3
AIPMT 2002
4

Solution of 0.1 N NH4OH and 0.1 N NH4Cl has pH 9.25. Then find out pKb of NH4OH

  1. 9.25
  2. 4.75
  3. 3.75
  4. 8.25
AIPMT 2002
5

In HS-, I-, R-NH2, NH3 order of proton accepting tendency will be

  1. I- > NH3 > R-NH2 > HS-
  2. NH3 > R-NH2 > HS- > I-
  3. R-NH2 > NH3 > HS- > I-
  4. HS- > R-NH2 > NH3 > I-
AIPMT 2001
6

Ionisation constant of CH3COOH is 1.7 10-5 and concentration of H+ ions is 3.4 10-4. Then find out initial concentration of CH3COOH molecules.

  1. 3.4 10-4
  2. 3.4 10-3
  3. 6.8 10-4
  4. 6.8 10-3
AIPMT 2001
7

Solubility of M2S salt is 3.5 10-6 then find out solubility product.

  1. 1.7 10-6
  2. 1.7 10-16
  3. 1.7 10-18
  4. 1.7 10-12
AIPMT 2001
8

Correct relation between dissociation constants of a dibasic acid is

  1. Ka1 = Ka2
  2. Ka1 > Ka2
  3. Ka1 < Ka2
  4. Ka1 = 1 Ka2
AIPMT 2001
9

For any reversible reaction, if we increase concentration of the reactants, then effect on equilibrium constant

  1. depends on amount of concentration
  2. unchanged
  3. decrease
  4. increase
AIPMT 2000
10

Conjugate acid of NH2- is

  1. NH4OH
  2. NH4+
  3. NH2-
  4. NH3
AIPMT 2000
11

Which statement is wrong about pH and H+?

  1. pH of neutral water is not zero.
  2. Adding 1 N solution of CH3COOH and 1 N solution of NaOH, pH will be seven.
  3. [H+] of dilute and hot H2SO4 is more than concentrated and cold H2SO4
  4. Mixing solution of CH3COOH and HCl. pH will be less than 7.
AIPMT 2000

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