d- and f-Block Elements · Question 13

Among Fe2+, Fe3+, Cr2+ and Zn2+, the ion that shows positive borax bead test and with highest ionisation enthalpy is :

1. Fe2+
2. Zn2+
3. Cr2+
4. Fe3+

Number of paramagnetic ions among the following d- and f-block metal ions is . Mn2+, Cu2+, Zn2+, Yb2+, Sc3+, La3+, Gd3+, Lu3+, Ti4+, Ce4+ (Atomic number of Mn = 25, Cu = 29, Zn = 30, Yb = 70, Sc = 21, La = 57, Gd = 64, Lu = 71, Ti = 22, Ce = 58)

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below

1. Statement I is false but Statement II is true
2. Both Statement I and Statement II are false
3. Both Statement I and Statement II are true
4. Statement I is true but Statement II is false

Consider the following statements about manganate and permanganate ions. Identify the correct statements. Choose the correct answer from the options given below :

1. A and D Only
2. A, B and C Only
3. A, C and D Only
4. A, D and E Only

"X" is an oxoanion of the lightest element of group 7 (in the periodic table). The metal is in +6 oxidation state in "X". The color of the potassium salt of X is

1. purple
2. orange
3. yellow
4. green

The oxidation state of chromium in the final product formed in the reaction between KI and acidified K2Cr2O7 solution is :

1. +2
2. +3
3. +4
4. +6

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is true but Statement II is false
2. Both Statement I and Statement II are true
3. Both Statement I and Statement II are false
4. Statement I is false but Statement II is true

Among the following oxides of 3d elements, the number of mixed oxides are . Ti2O3, V2O4, Cr2O3, Mn3O4, Fe3O4, Fe2O3, Co3O4

MnO42-, in acidic medium, disproportionates to :

1. MnO4- and MnO
2. MnO4- and MnO2
3. Mn2O7 and MnO2
4. Mn2O7 and MnO

Consider the following reactions : NaCl + K2Cr2O7 + H2SO4 A + KHSO4 + NaHSO4 + H2O A + NaOH B + NaCl + H2O B + H2SO4 + H2O2 C + Na2SO4 + H2O In the product 'C', 'X' is the number of O22- units, 'Y' is the total number of oxygen atoms present and 'Z' is the oxidation state of Cr. The value of X + Y + Z is .