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Solutions · Question 39

JEE Main 2025 (Online) 28th January Evening ShiftMCQMedium📈 Topic in 26% papers+4−1
1

Assume a living cell with 0.9% (w/w) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data upto first decimal place only) The cell will :

  1. shrink since solution is 0.45% (w/w) as a result of association of glucose molecules (due to hydrogen bonding)
  2. shrink since solution is 0.5% (w/w)
  3. show no change in volume since solution is 0.9% (w/w)
  4. swell up since solution is 1% (w/w)

Answer

Solution

Outside solution: equal mole fractions nglucose = nwater.

Take 1 mol of each: mass of glucose = 180 g, mass of water = 18 g.

% (w/w) of glucose = 180180 + 18 100 = 90.9\%

Cell sap: 0.9% (w/w) glucose, i.e. xglucose = 0.9/1800.9/180 + 99.1/18 9 10-4.

The outside solution is far more concentrated (hypertonic); water moves out of the cell by osmosis and the cell shrinks.

None of the options gives the correct concentration of the outside solution (90.9% w/w), so no option is fully correct; the question was awarded as bonus.

Answer: No option is correct (the cell shrinks).

JEE Main 2025 (Online) 28th January Evening Shift

Keep practising — Solutions

2

Given below are two statements : Given : Molar mass of C, H, O, Cl are 12, 1, 16 and 35.5 g mol-1, respectively In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
JEE Main 2026 (Online) 8th April Evening Shift
3

Which of the following statements are not correct? Choose the correct answer from the options given below :

  1. A and B only
  2. A and D only
  3. A, B and D only
  4. A, C and D only
JEE Main 2026 (Online) 8th April Evening Shift
4

When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a solvent the vapor pressure of solution was x% of vapor pressure of pure solvent. What is x% ?

  1. 50%
  2. 60%
  3. 70%
  4. 80%
JEE Main 2026 (Online) 6th April Morning Shift
5

Given below are two statements : [figure] In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
JEE Main 2026 (Online) 6th April Evening Shift
6

What is the mole fraction of water in 10% by weight (w/w) of aqueous urea solution? [Given: Molar mass of H, O, C and N are 1, 16, 12 and 14 g mol-1 respectively.]

  1. 0.825
  2. 0.032
  3. 0.867
  4. 0.967
JEE Main 2026 (Online) 5th April Morning Shift
7

20 g hemoglobin in a 1 L aqueous solution (A) at 300 K is separated from pure water by semi permeable membrane. At equilibrium the height of solution in a tube dipped in a solution (A) is found to be 80.0 mm higher than the tube dipped in water. The molar mass of hemoglobin is kg mol-1. (Nearest integer) (Given : g = 10 m s-2, R = 8.3 kPa dm3 K-1 mol-1, density of solution = 1000 kg m-3)

JEE Main 2026 (Online) 5th April Evening Shift
8

A non-volatile, non-electrolyte solid solute when dissolved in 40 g of a solvent, the vapour pressure of the solvent decreased from 760 mm Hg to 750 mm Hg. If the same solution boils at 320 K, then the number of moles of the solvent present in the solution is . (Nearest integer) [Given: boiling point of the pure solvent = 319.5 K, Kb of the solvent = 0.3 K kg mol-1]

JEE Main 2026 (Online) 4th April Morning Shift
9

At 27 °C, 0.1 M, 1 L K4[Fe(CN)6] aqueous solution and 0.1 M, 1 L FeCl3 aqueous solution are placed in a container separated by a semi permeable membrane AB. Assume complete dissociation of both the solutes. Which of the following statement is correct? [figure]

  1. Blue color is formed on both sides.
  2. Ionic solutes in aqueous solution can pass through semi-permeable membrane.
  3. Solution on side 'y' is hypotonic.
  4. To cause the reverse flow of solvent during osmosis, external pressure (any value) should be applied to side 'x'.
JEE Main 2026 (Online) 4th April Evening Shift
10

19.5 g of fluoro acetic acid (molar mass = 78 g mol-1) is dissolved in 500 g of water at 298 K. The depression in the freezing point of water was 1°C. What is Ka of fluoro acetic acid ? (For water, Kf = 1.86 K kg mol-1). Assume molarity and molality to have same values.

  1. 10-6
  2. 4 10-4
  3. 3 10-5
  4. 3 10-3
JEE Main 2026 (Online) 2nd April Morning Shift
11

Solution A is prepared by dissolving 1 g of a protein (molar mass = 50,000 g mol-1) in 0.5 L of water at 300 K. Its osmotic pressure is x bar. Solution B is made by dissolving 2 g of the same protein in 1 L of water at 300 K. Osmotic pressure of solution B is y bar. Entire solution of A is mixed with entire solution of B at the same temperature. The osmotic pressure of resultant solution is z bar. x, y and z respectively are: (R = 0.083 L bar mol-1 K-1)

  1. 9.96 10-4; 9.96 10-4; 9.96 10-4
  2. 9.96 10-4; 9.96 10-4; 19.92 10-4
  3. 4.98 10-4; 4.98 10-4; 9.96 10-4
  4. 4.98 10-4; 4.98 10-4; 4.98 10-4
JEE Main 2026 (Online) 2nd April Evening Shift

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