Chemical Kinetics · Question 18

For the thermal decomposition of reactant AB(g), the following plot is constructed. [figure] The half-life of the reaction is 'x' min. x = min. (Nearest integer)

[figure] Given above is the concentration vs time plot for a dissociation reaction : A nB. Based on the data of the initial phase of the reaction (initial 10 min), the value of n is .

1. 2
2. 5
3. 4
4. 3

Observe the following reactions at T(K). I. A products. II. 5Br-(aq) + BrO3-(aq) + 6H+(aq) 3Br2(aq) + 3H2O(l) Both the reactions are started at 10.00 am. The rates of these reactions at 10.10 am are same. The value of - [Br-] t at 10.10 am is 2 10-4 mol L-1 min-1. The concentration of A at 10.10 am is 10-2 mol L-1. What is the first order rate constant (in min-1) of reaction I?

1. 4 10-3
2. 2 10-3
3. 10-3
4. 10-2

A product (First order reaction). Three sets of experiments were performed for a reaction under similar experimental conditions: Run 1 100 mL of 10 M solution of reactant A Run 2 200 mL of 10 M solution of reactant A Run 3 100 mL of 10 M solution of reactant A + 100 mL of H2O added. The correct variation of rate of reaction is

1. Run 1 = Run 2 = Run 3
2. Run 3 < Run 1 < Run 2
3. Run 1 < Run 2 < Run 3
4. Run 3 < Run 1 = Run 2

The temperature at which the rate constants of the given below two gaseous reactions become equal is K. (Nearest integer) X Y, k1 = 106 e -30000T P Q, k2 = 104 e -24000T Given : 10 = 2.303

Correct statements regarding Arrhenius equation among the following are : Choose the correct answer from the options given below :

1. A and B Only
2. B and D Only
3. B and C Only
4. A and C Only

Consider A k1 B and C k2 D are two reactions. If the rate constant (k1) of the A B reaction can be expressed by the following equation 10 k = 14.34 - 1.5 104T/K and activation energy of C D reaction (Ea2) is 15th of the A B reaction (Ea1), then the value of (Ea2) is kJ mol-1. (Nearest Integer)

Pre-exponential factors of two different reactions of same order are identical. Let activation energy of first reaction exceed the activation energy of second reaction by 20 kJ mol-1. If k1 and k2 are the rate constants of first and second reaction respectively at 300 K, then k2k1 will be . (nearest integer) [R = 8.3 J K-1 mol-1]

Decomposition of A is a first order reaction at T(K) and is given by A(g) B(g) + C(g). In a closed 1 L vessel, 1 bar A(g) is allowed to decompose at T(K). After 100 minutes, the total pressure was 1.5 bar. What is the rate constant (in min-1) of the reaction? ( 2 = 0.3)

1. 6.9 10-4
2. 6.9 10-3
3. 6.9 10-1
4. 6.9 10-2

In a first order decomposition reaction, the time taken for the decomposition of reactant to one fourth and one eighth of its initial concentration are t1 and t2 (s), respectively. The ratio t1/t2 will be:

1. 43
2. 32
3. 34
4. 23