Which of the following statements is not true for halogens?
- All are oxidizing agents.
- All form monobasic oxyacids.
- All but fluorine show positive oxidation states.
- Chlorine has the highest electron-gain enthalpy.
Answer
(3) All but fluorine show positive oxidation states.
Solution
(1) All halogens readily accept an electron ⇒ all are oxidising agents (F2 the strongest). True.
(2) Oxoacids such as HOF, HOCl, HClO4, HIO4 contain one ionisable –OH ⇒ monobasic. True.
(4) As per NCERT, chlorine has the most negative electron gain enthalpy in the group (fluorine is less because of its small size). True.
(3) As per NCERT, all halogens show the −1 oxidation state; chlorine, bromine and iodine show −1 as well as +1, +3, +5 and +7. So halogens other than fluorine do not show only positive oxidation states — the statement is not true.
Answer: (3)