Thermodynamics · Question 35

Standard enthalpy of vaporisation vapH for water at 100 C is 40.66 kJ mol-1. The internal energy of vaporisation of water at 100 C (in kJ mol-1) is

1. +37.56
2. -43.76
3. +43.76
4. +40.66

Consider the following processes : array|l|c| & H (kJ/mol) \ 12A B & +150 \ 3B 2C + D & -125 \ E + A 2D & +350 \ array For B + D E + 2C, H will be

1. 525 kJ/mol
2. -175 kJ/mol
3. -325 kJ/mol
4. 325 kJ/mol

If the enthalpy change for the transition of liquid water to steam is 30 kJ mol-1 at 27 , the entropy change for the process would be

1. 10 J mol-1 K-1
2. 1.0 J mol-1 K-1
3. 0.1 J mol-1 K-1
4. 100 J mol-1 K-1

Enthalpy change for the reaction, 4H(g) 2H2(g) is -869.6 kJ The dissociation energy of H-H bond is

1. -434.8 kJ
2. -869.6 kJ
3. +434.8 kJ
4. +217.4 kJ

Which of the following is correct option for free expansion of an ideal gas under adiabatic condition ?

1. q = 0, T 0, w = 0
2. q 0, T = 0, w = 0
3. q = 0, T = 0, w = 0
4. q = 0, T < 0, w 0

Match List I (Equations) with List II (Type of processes) and select the correct option.

1. A - (i), B - (ii), C - (iii), D - (iv)
2. A - (iii), B - (iv), C - (ii), D - (i)
3. A - (iv), B - (i), C - (ii), D - (iii)
4. A - (ii), B - (i), C - (iv), D - (iii)

Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be

1. infinite
2. 3 Joules
3. 9 Joules
4. zero

For vaporization of water at 1 atmospheric pressure, the values of H and S are 40.63 kJ mol-1 and 108.8 J K-1 mol-1, respectively. The temperature when Gibbs energy change ( G) for this transformation will be zero, is

1. 273.4 K
2. 393.4 K
3. 373.4 K
4. 293.4 K

The following two reactions are known Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g); H = -26.8 kJ FeO(s) + CO(g) Fe(s) + CO2(g); H = -16.5 kJ The value of H for the following reaction Fe2O3(s) + CO(g) 2FeO(s) + CO2(g) is

1. +10.3 kJ
2. -43.3 kJ
3. -10.3 kJ
4. +6.2 kJ

Standard entropies of X2, Y2 and XY3 are 60, 40 and 50 J K-1 mol-1 respectively. For the reaction 12X2 + 32Y2 XY3, H = -30 kJ, to be at equilibrium, the temperature should be

1. 750 K
2. 1000 K
3. 1250 K
4. 500 K