Among the following halogens F2, Cl2, Br2 and I2 Which can undergo disproportionation reactions?
- F2 and Cl2
- Cl2, Br2 and I2
- Only I2
- F2, Cl2 and Br2
Answer
(2) Cl2, Br2 and I2
Solution
Disproportionation: the same element is oxidised and reduced at the same time, e.g.
0Cl2 + 2OH- -1Cl- + +1OCl- + H2O
Br2 and I2 react in the same way.
F, the most electronegative element, shows only −1 (no positive oxidation state), so F2 cannot disproportionate.
Hence Cl2, Br2 and I2.
Answer: (2)