Which of the following statements is correct for the spontaneous adsorption of a gas?
- is negative and, therefore, should be highly positive.
- is negative and, therefore, should be highly negative.
- is positive and, therefore, should be negative.
- is positive and, therefore, should also be highly positive.
Answer
(2) is negative and, therefore, should be highly negative.
Solution
As per NCERT, when a gas is adsorbed, the freedom of movement of its molecules becomes restricted ⇒ is negative.
For a spontaneous process, = - T must be negative.
∵ -T is positive, ∴ must be highly negative (adsorption is exothermic) so that < 0.
Answer: (2)