PYQSide ExamsMy practice

Aldehydes, Ketones and Carboxylic Acids · Question 73

AIPMT 2003MCQMedium📈 Topic in 38% papers+4−1
1

A and B in the following reactions are : [figure]

  1. [figure]
  2. [figure]
  3. A = RR'CHCN, B = NaOH
  4. [figure]

Answer

(4) [figure]

Solution

Step 1: HCN/KCN adds to the carbonyl group (nucleophilic addition of CN-) to give the cyanohydrin:

R-CO-R' [KCN]HCN RR'C(OH)CN (A)

Step 2: The product RR'C(OH)CH2NH2 has -CH2NH2 in place of -C N the nitrile group is reduced.

As per NCERT, nitriles are reduced to primary amines by LiAlH4: -C N LiAlH4 -CH2NH2 B = LiAlH4

Answer: (4)

AIPMT 2003

Keep practising — Aldehydes, Ketones and Carboxylic Acids

2

[figure] In the above reaction product P is

  1. [figure]
  2. [figure]
  3. [figure]
  4. C6H5- O \|C-C6H5
AIPMT 2002
3

In the following reaction product P is R- O \|C-Cl [Pd-BaSO4]H2 P

  1. RCH2OH
  2. RCOOH
  3. RCHO
  4. RCH3
AIPMT 2002
4

[figure] Product 'P' in the above reaction is

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2002
5

First product of the reaction between RCHO and NH2NH2 is

  1. RCH=NNH2
  2. RCH=NH
  3. RCH2NH2
  4. RCON3
AIPMT 2000
6

Benzoic acid may be converted into ethyl benzoate by reaction with :

  1. ethyl alcohol
  2. ethyl alcohol and dry HCl
  3. ethyl chloride
  4. sodium ethoxide.
AIPMT 2000
7

Reduction by LiAlH4 of hydrolysed product of an ester gives

  1. two alcohols
  2. two aldehydes
  3. one acid and one alcohol
  4. two acids.
AIPMT 2000

All Aldehydes, Ketones and Carboxylic Acids PYQs →

PDFDownload Aldehydes, Ketones and Carboxylic Acids PYQs as PDF Free, with answer key and a QR code to every solution — print it or study offline⬇
All NEET Chemistry chapters
Physical ChemistrySome Basic Concepts of ChemistryStructure of AtomStates of MatterThermodynamicsEquilibriumRedox ReactionsSolid StateSolutionsElectrochemistryChemical KineticsSurface Chemistry
Inorganic ChemistryClassification of Elements and Periodicity in PropertiesChemical Bonding and Molecular StructureHydrogens-Block Elementsp-Block Elements (Group 13 & 14)Environmental ChemistryGeneral Principles of Isolation of Elementsp-Block Elements (Group 15–18)d- and f-Block ElementsCoordination Compounds
Organic ChemistryOrganic Chemistry – Some Basic Principles and TechniquesIsomerismHydrocarbonsHaloalkanes and HaloarenesAlcohols, Phenols and EthersAldehydes, Ketones and Carboxylic AcidsAminesBiomoleculesPolymersChemistry in Everyday LifePrinciples Related to Practical Chemistry