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d- and f-Block Elements · Question 3

JEE Main 2026 (Online) 6th April Morning ShiftMCQMedium📈 Topic in 10% papers+4−1
1

The correct statements among the following are : Choose the correct answer from the options given below :

  1. A and B Only
  2. A, C and D Only
  3. C and D Only
  4. B, C and D Only

Answer

(3) C and D Only

Solution

A. Vanadium(V) oxide, V2O5, is the catalyst of the Contact process for H2SO4, but it is amphoteric (mainly acidic), not basic ⇒ false

B. Ziegler–Natta catalyst = TiCl4 + Al(C2H5)3

In TiCl4, Ti4+ = [Ar] 3d0 ⇒ n = 0 ⇒ = n(n+2) = 0 BM (2.84 BM needs n = 2) ⇒ false

C. The p-block compound is Al(C2H5)3, in which Al is in the +3 state ⇒ true

D. Wacker process uses PdCl2; Pd2+ = [Kr] 4d8 ⇒ 8 electrons in the outermost d orbitals ⇒ true

∴ C and D only

Answer: (3)

JEE Main 2026 (Online) 6th April Morning Shift

Keep practising — d- and f-Block Elements

2

The correct order of first ( iH1) and second ( iH2) ionisation enthalpy values of Cr and Mn are : Choose the correct answer from the options given below :

  1. A and B only
  2. B and C only
  3. A and D only
  4. C and D only
JEE Main 2026 (Online) 6th April Evening Shift
3

Which of the following is NOT a physical or chemical characteristics of interstitial compounds?

  1. They have high melting points, higher than those of pure metals.
  2. They are very soft and ionic in nature.
  3. They retain metallic conductivity.
  4. They are chemically inert and usually non-stoichiometric.
JEE Main 2026 (Online) 5th April Morning Shift
4

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are correct
  2. Both Statement I and Statement II are incorrect
  3. Statement I is correct but Statement II is incorrect
  4. Statement I is incorrect but Statement II is correct
JEE Main 2026 (Online) 5th April Evening Shift
5

The correct statements among the following are, Choose the correct answer from the options given below :

  1. A and B Only
  2. C and D Only
  3. B and D Only
  4. A and C Only
JEE Main 2026 (Online) 4th April Morning Shift
6

Correct statements from the following are Choose the correct answer from the options given below :

  1. A, B and C Only
  2. A, C and D Only
  3. A and C Only
  4. B and D Only
JEE Main 2026 (Online) 4th April Morning Shift
7

Match the LIST-I with LIST-II Choose the correct answer from the options given below :

  1. A-I, B-III, C-IV, D-II
  2. A-II, B-I, C-III, D-IV
  3. A-IV, B-II, C-I, D-III
  4. A-III, B-I, C-IV, D-II
JEE Main 2026 (Online) 4th April Morning Shift
8

Pairs of elements with the same number of electrons in their respective 4f orbital are [Atomic number. Eu-63, Gd-64, Dy-66, Ho-67, Tm-69, Yb-70, Lu-71, Hf-72] Choose the correct answer from the options given below :

  1. B and C Only
  2. A and B Only
  3. A and D Only
  4. A and C Only
JEE Main 2026 (Online) 4th April Evening Shift
9

Consider |x| is the difference in oxidation states of Mn in highest manganese fluoride and highest manganese oxide. The ions with |x| number of unpaired electrons from the following are : Choose the correct answer from the options given below :

  1. A and B Only
  2. C, D and E Only
  3. C and E Only
  4. B and E Only
JEE Main 2026 (Online) 4th April Evening Shift
10

Which of the following sets includes all the species that will change the orange colour of K2Cr2O7 in acidic medium ?

  1. Fe2+, Sn2+, I-, S2-
  2. S2-, Fe3+, I-, C2O42-
  3. Fe2+, NO2-, SO2, Sn4+
  4. Fe3+, SO42-, S2-, Sn4+
JEE Main 2026 (Online) 2nd April Morning Shift
11

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

  1. Both Statement I and Statement II are true
  2. Both Statement I and Statement II are false
  3. Statement I is true but Statement II is false
  4. Statement I is false but Statement II is true
JEE Main 2026 (Online) 2nd April Evening Shift

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