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Chemical Bonding and Molecular Structure · Question 60

AIPMT 2012 (Prelims)MCQEasy📈 Topic in 75% papers+4−1
1

Which of the following species contains three bond pairs and one lone pair around the central atom ?

  1. H2O
  2. BF3
  3. NH2-
  4. PCl3

Answer

(4) PCl3

Solution

H2O: 2 bond pairs + 2 lone pairs on O.

BF3: 3 bond pairs + 0 lone pair on B.

NH2-: 2 bond pairs + 2 lone pairs on N.

PCl3: P has 5 valence electrons; 3 are used in P–Cl bonds ⇒ 3 bond pairs + 1 lone pair (pyramidal).

Answer: (4)

AIPMT 2012 (Prelims)

Keep practising — Chemical Bonding and Molecular Structure

2

The pair of species with the same bond order is

  1. O22-, B2
  2. O2+, NO+
  3. NO, CO
  4. N2, O2
AIPMT 2012 (Prelims)
3

Which of the following structures is the most preferred and hence of lowest energy for SO3?

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
AIPMT 2011 (Mains)
4

The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description?

  1. O2-, O22- – Both diamagnetic
  2. O2+, O2 – Both paramagnetic
  3. O, O22- – Both paramagnetic
  4. O+, O22- – Both paramagnetic
AIPMT 2011 (Mains)
5

Which of the following has the minimum bond length ?

  1. O2+
  2. O2-
  3. O22-
  4. O2
AIPMT 2011 (Prelims)
6

Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals, NO2-, NO3-, NH2-, NH4+, SCN-?

  1. NO2- and NO3-
  2. NH4+ and NO3-
  3. SCN- and NH2-
  4. NO2- and NH2-
AIPMT 2011 (Prelims)
7

The correct order of increasing bond length of C-H, C-O, C-C and C=C is

  1. C-H < C=C < C-O < C-C
  2. C-C < C=C < C-O < C-H
  3. C-O < C-H < C-C < C=C
  4. C-H < C-O < C-C < C=C
AIPMT 2011 (Prelims)
8

The pairs of species of oxygen and their magnetic behavior are noted below. Which of the following presents the correct description?

  1. O2-, O22- - Both diamagnetic
  2. O+, O22- - Both paramagnetic
  3. O2+, O2 - Both paramagnetic
  4. O, O22- - Both paramagnetic
AIPMT 2011 (Prelims)
9

Considering the state of hybridization of carbon atoms, find out the molecule among the following which is linear ?

  1. CH3-CH=CH-CH3
  2. CH3-C C-CH3
  3. CH2=CH-CH2-C CH
  4. CH3-CH2-CH2-CH3
AIPMT 2011 (Prelims)
10

Which of the following compounds has the lowest melting point?

  1. CaCl2
  2. CaBr2
  3. CaI2
  4. CaF2
Out of syllabusAIPMT 2011 (Prelims)
11

In which of the following molecules the central atom does not have sp3 hybridization?

  1. CH4
  2. SF4
  3. BF4-
  4. NH4+
AIPMT 2010 (Mains)

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