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Principles Related to Practical Chemistry · Question 45

JEE Main 2025 (Online) 3rd April Morning ShiftNumericalEasy📈 Topic in 65% papers+4
1

0.5 g of an organic compound on combustion gave 1.46 g of CO2 and 0.9 g of H2O. The percentage of carbon in the compound is . (Nearest integer) [Given : Molar mass (in g mol-1) C : 12, H : 1, O : 16]

Answer

80

Solution

∵ 44 g of CO2 contains 12 g of C

⇒ Mass of C in 1.46 g CO2 = 1244 1.46 = 0.398 g

∴ % of C = 0.3980.5 100

= 79.6\% 80\%

Answer: 80

JEE Main 2025 (Online) 3rd April Morning Shift

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2

Compounds that should not be used as primary standards in titrimetric analysis are : Choose the most appropriate answer from the options given below:

  1. C, D and E Only
  2. B and D Only
  3. D and E Only
  4. A, C and D Only
JEE Main 2025 (Online) 3rd April Evening Shift
3

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at 300 K = 15 mm Hg)

  1. 15.71\%
  2. 17.46\%
  3. 7.85\%
  4. 20.95\%
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4

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

  1. A, D and E only
  2. A, B and C only
  3. B, D and E only
  4. C, D and E only
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5

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

  1. 20.87
  2. 12.57
  3. 1.257
  4. 18.67
JEE Main 2025 (Online) 2nd April Evening Shift
6

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

  1. Sulphide ion
  2. Sulphite ion
  3. Sulphate ion
  4. Sodium ion
JEE Main 2025 (Online) 2nd April Evening Shift
7

Match List-I with List-II. Choose the correct answer from the options given below:

  1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
  4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
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8

The steam volatile compounds among the following are : Choose the correct answer from the options given below :

  1. (B) and (D) Only
  2. (A), (B) and (C) Only
  3. (A) and (B) Only
  4. (A) and (C) Only
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9

Given below are two statements: In the light of the above statements, choose the correct answer from the options given below

  1. Statement I is false but Statement II is true
  2. Statement I is true but Statement II is false
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
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10

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is

  1. Cr3+
  2. Ti3+
  3. Ni2+
  4. Mn2+
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11

The purification method based on the following physical transformation is : (X)Solid Heat (X)Vapour Cool (X)Solid

  1. Extraction
  2. Crystallization
  3. Distillation
  4. Sublimation
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