Amines

Number of amine compounds from the following giving solids which are soluble in NaOH upon reaction with Hinsberg's reagent is . [figure]

Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :

1. Statement I is false but Statement II is true
2. Both Statement I and Statement II are true
3. Both Statement I and Statement II are false
4. Statement I is true but Statement II is false

9.3 g of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is g. (nearest integer)

An amine (X) is prepared by ammonolysis of benzyl chloride. On adding p-toluenesulphonyl chloride to it the solution remains clear. Molar mass of the amine (X) formed is g mol-1. (Given molar mass in g mol-1 C : 12, H : 1, O : 16, N : 14)

9.3 g of pure aniline is treated with bromine water at room temperature to give a white precipitate of the product 'P'. The mass of product 'P' obtained is 26.4 g. The percentage yield is %.

X g of ethanamine was subjected to reaction with NaNO2/HCl followed by hydrolysis to liberate N2 and HCl. The HCl generated was completely neutralised by 0.2 moles of NaOH. X is g.

Xg of ethylamine is subjected to reaction with NaNO2/HCl followed by water; evolved dinitrogen gas which occupied 2.24 L volume at STP. X is 10-1 g.

From 6.55 g of aniline, the maximum amount of acetanilide that can be prepared will be 10-1 g.

Phthalimide is made to undergo following sequence of reactions. [figure] Total number of bonds present in product 'P' is/are .

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :

1. Both Statement I and Statement II are correct
2. Both Statement I and Statement II are incorrect
3. Statement I is correct but Statement II is incorrect
4. Statement I is incorrect but Statement II is correct