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Chemical Bonding and Molecular Structure · Question 5

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1

Match the species in List-I with their geometry in List-II.

  1. A-III, B-II, C-I, D-IV
  2. A-IV, B-III, C-I, D-II
  3. A-III, B-IV, C-I, D-II
  4. A-III, B-I, C-II, D-IV

Answer

(3) A-III, B-IV, C-I, D-II

Solution

A. PCl5: sp3d hybridization with 5 bond pairs and 0 lone pairs Trigonal bipyramidal (III).

B. BrF5: sp3d2 hybridization with 5 bond pairs and 1 lone pair Square pyramidal (IV).

C. BF4-: sp3 hybridization with 4 bond pairs and 0 lone pairs Tetrahedral (I).

D. [Ni(CN)4]2-: Ni2+ (3d8) with strong field ligand CN- undergoes pairing to give dsp2 hybridization Square Planar (II).

Matching: A-III, B-IV, C-I, D-II. Answer: (3)

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2

Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Statement I is true but Statement II is false
  2. Statement I is false but Statement II is true
  3. Both Statement I and Statement II are true
  4. Both Statement I and Statement II are false
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3

Match List-I with List-II Choose the correct answer from the options given below :

  1. A-IV, B-II, C-III, D-I
  2. A-IV, B-II, C-I, D-III
  3. A-II, B-I, C-IV, D-III
  4. A-II, B-I, C-III, D-IV
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4

Identify the correct orders against the property mentioned Choose the correct answer from the options given below:

  1. A, C only
  2. B, C only
  3. A, D only
  4. B, D only
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5

Match List I with List II. Choose the correct answer from the options given below :

  1. A-I, B-IV, C-II, D-III
  2. A-IV, B-III, C-II, D-I
  3. A-III, B-IV, C-II, D-I
  4. A-III, B-IV, C-I, D-II
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6

Intramolecular hydrogen bonding is present in

  1. [figure]
  2. [figure]
  3. [figure]
  4. HF
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7

Match List I with List II. Choose the correct answer from the options given below:

  1. A-I, B-IV, C-II, D-III
  2. A-II, B-IV, C-III, D-I
  3. A-III, B-IV, C-I, D-II
  4. A-II, B-III, C-IV, D-I
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8

Identify the correct answer.

  1. Three resonance structures can be drawn for ozone
  2. BF3 has non-zero dipole moment
  3. Dipole moment of NF3 is greater than that of NH3
  4. Three canonical forms can be drawn for CO32- ion
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9

Which of the following molecules has "NON ZERO" dipole moment value?

  1. CCl4
  2. HI
  3. CO2
  4. BF3
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10

Identify the incorrect statement about PCl5.

  1. PCl5 possesses two different Cl-P-Cl bond angles
  2. All five P-Cl bonds are identical in length
  3. PCl5 exhibits sp3d hybridisation
  4. PCl5 consists of five P-Cl (sigma) bonds
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11

Match List-I with List-II: Choose the correct answer from the options given below:

  1. A-III, B-IV, C-I, D-II
  2. A-IV, B-I, C-III, D-II
  3. A-IV, B-III, C-II, D-I
  4. A-IV, B-III, C-I, D-II
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