Chemical Bonding and Molecular Structure · Question 11

Identify the correct answer.

1. Three resonance structures can be drawn for ozone
2. BF3 has non-zero dipole moment
3. Dipole moment of NF3 is greater than that of NH3
4. Three canonical forms can be drawn for CO32- ion

Which of the following molecules has "NON ZERO" dipole moment value?

1. CCl4
2. HI
3. CO2
4. BF3

Identify the incorrect statement about PCl5.

1. PCl5 possesses two different Cl-P-Cl bond angles
2. All five P-Cl bonds are identical in length
3. PCl5 exhibits sp3d hybridisation
4. PCl5 consists of five P-Cl (sigma) bonds

Match List-I with List-II: Choose the correct answer from the options given below:

1. A-III, B-IV, C-I, D-II
2. A-IV, B-I, C-III, D-II
3. A-IV, B-III, C-II, D-I
4. A-IV, B-III, C-I, D-II

Amongst the following, the total number of species NOT having eight electrons around central atom in its outermost shell, is NH3, AlCl3, BeCl2, CCl4, PCl5

1. 2
2. 4
3. 1
4. 3

The correct order of energies of molecular orbitals of N2 molecule, is

1. 1s < 1s < 2s < 2s < 2pz < ( 2px = 2py) < ( 2px = 2py) < 2pz
2. 1s < 1s < 2s < 2s < 2pz < 2pz < ( 2px = 2py) < ( 2px = 2py)
3. 1s < 1s < 2s < 2s < ( 2px = 2py) < ( 2px = 2py) < 2pz < 2pz
4. 1s < 1s < 2s < 2s < ( 2px = 2py) < 2pz < ( 2px = 2py) < 2pz

Amongst the following which one will have maximum 'lone pair - lone pair' electron repulsions?

1. ClF3
2. IF5
3. SF4
4. XeF2

Which amongst the following is incorrect statement?

1. The bond orders of O2+, O2, O2- and O22- are 2.5, 2, 1.5 and 1, respectively
2. C2 molecule has four electrons in its two degenerate molecular orbitals
3. H2+ ion has one electron
4. O2+ ion is diamagnetic

Match List-I with List-II : Choose the correct answer from the options given below :

1. (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
2. (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
3. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
4. (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)

The correct order of bond angles in the following compounds/species is :

1. CO2 < NH3 < H2O < +NH4
2. H2O < NH3 < +NH4 < CO2
3. H2O < +NH4 < NH3 < CO2
4. H2O < +NH4 = NH3 < CO2