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Chemical Bonding and Molecular Structure · Question 10

NEET (UG) 2024MCQEasy📈 Topic in 12% papers+4−1
1

Intramolecular hydrogen bonding is present in

  1. [figure]
  2. [figure]
  3. [figure]
  4. HF

Answer

(1) [figure]

Solution

In o-nitrophenol the –OH and -NO2 groups are on adjacent carbons, so the H of –OH forms a hydrogen bond with an O of -NO2 within the same molecule (a six-membered chelate ring): intramolecular H-bonding.

p-Nitrophenol and m-nitrophenol: the groups are too far apart → only intermolecular H-bonding.

HF: intermolecular H-bonding (zig-zag chains).

Answer: (1)

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2

Match List I with List II. Choose the correct answer from the options given below:

  1. A-I, B-IV, C-II, D-III
  2. A-II, B-IV, C-III, D-I
  3. A-III, B-IV, C-I, D-II
  4. A-II, B-III, C-IV, D-I
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3

Identify the correct answer.

  1. Three resonance structures can be drawn for ozone
  2. BF3 has non-zero dipole moment
  3. Dipole moment of NF3 is greater than that of NH3
  4. Three canonical forms can be drawn for CO32- ion
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4

Which of the following molecules has "NON ZERO" dipole moment value?

  1. CCl4
  2. HI
  3. CO2
  4. BF3
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5

Identify the incorrect statement about PCl5.

  1. PCl5 possesses two different Cl-P-Cl bond angles
  2. All five P-Cl bonds are identical in length
  3. PCl5 exhibits sp3d hybridisation
  4. PCl5 consists of five P-Cl (sigma) bonds
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6

Match List-I with List-II: Choose the correct answer from the options given below:

  1. A-III, B-IV, C-I, D-II
  2. A-IV, B-I, C-III, D-II
  3. A-IV, B-III, C-II, D-I
  4. A-IV, B-III, C-I, D-II
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7

Amongst the following, the total number of species NOT having eight electrons around central atom in its outermost shell, is NH3, AlCl3, BeCl2, CCl4, PCl5

  1. 2
  2. 4
  3. 1
  4. 3
NEET (UG) 2023
8

The correct order of energies of molecular orbitals of N2 molecule, is

  1. 1s < 1s < 2s < 2s < 2pz < ( 2px = 2py) < ( 2px = 2py) < 2pz
  2. 1s < 1s < 2s < 2s < 2pz < 2pz < ( 2px = 2py) < ( 2px = 2py)
  3. 1s < 1s < 2s < 2s < ( 2px = 2py) < ( 2px = 2py) < 2pz < 2pz
  4. 1s < 1s < 2s < 2s < ( 2px = 2py) < 2pz < ( 2px = 2py) < 2pz
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9

Amongst the following which one will have maximum 'lone pair - lone pair' electron repulsions?

  1. ClF3
  2. IF5
  3. SF4
  4. XeF2
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10

Which amongst the following is incorrect statement?

  1. The bond orders of O2+, O2, O2- and O22- are 2.5, 2, 1.5 and 1, respectively
  2. C2 molecule has four electrons in its two degenerate molecular orbitals
  3. H2+ ion has one electron
  4. O2+ ion is diamagnetic
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11

Match List-I with List-II : Choose the correct answer from the options given below :

  1. (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
  2. (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)
  3. (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
  4. (a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
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