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Chemical Bonding and Molecular Structure

JEE Main 2024 (Online) 31st January Morning ShiftMCQEasy📈 Topic in 29% papers+4−1
Ques. 1JEE Main 2024, 31 January (Morning Shift)

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals Choose the most appropriate from the options given below:

  1. B, C, D only
  2. A, B, C only
  3. B and D only
  4. A and C only

Answer

(4) A and C only

Solution

Conditions for LCAO:

(i) same or nearly the same energy ⇒ A is correct

(ii) same symmetry about the molecular axis ⇒ C is correct, D is wrong

(iii) maximum overlap ⇒ B (minimum overlap) is wrong

∴ A and C only

Answer: (4)

Keep practising — Chemical Bonding and Molecular Structure

Ques. 2JEE Main 2024, 31 January (Morning Shift)

The number of species from the following in which the central atom uses sp3 hybrid orbitals in its bonding is . NH3, SO2, SiO2, BeCl2, CO2, H2O, CH4, BF3

Ques. 3JEE Main 2024, 31 January (Evening Shift)

Which of the following is least ionic?

  1. CoCl2
  2. KCl
  3. BaCl2
  4. AgCl
Ques. 4JEE Main 2024, 31 January (Evening Shift)

A diatomic molecule has a dipole moment of 1.2 D. If the bond distance is 1 Å, then fractional charge on each atom is 10-1 esu. (Given 1 D = 10-18 esucm)

Ques. 5JEE Main 2024, 30 January (Morning Shift)

Match List I with List II. Choose the correct answer from the options given below :

  1. A-I, B-II, C-IV, D-III
  2. A-IV, B-III, C-I, D-II
  3. A-III, B-IV, C-I, D-II
  4. A-II, B-I, C-III, D-IV
Ques. 6JEE Main 2024, 30 January (Morning Shift)

The total number of molecular orbitals formed from 2s and 2p atomic orbitals of a diatomic molecule is .

Ques. 7JEE Main 2024, 30 January (Evening Shift)

Given below are two statements: In the light of the above statements, choose the most appropriate from the options given below:

  1. Statement I is true but Statement II is false.
  2. Both Statement I and Statement II are true.
  3. Both Statement I and Statement II are false.
  4. Statement I is false but Statement II is true.
Ques. 8JEE Main 2024, 30 January (Evening Shift)

The molecule / ion with square pyramidal shape is

  1. PCl5
  2. [Ni(CN)4]2-
  3. PF5
  4. BrF5
Ques. 9JEE Main 2024, 29 January (Morning Shift)

The number of species from the following which are paramagnetic and with bond order equal to one is . H2, He2+, O2+, N22-, O22-, F2, Ne2+, B2

Ques. 10JEE Main 2024, 29 January (Morning Shift)

Number of compounds with one lone pair of electrons on central atom amongst following is . O3, H2O, SF4, ClF3, NH3, BrF5, XeF4

Ques. 11JEE Main 2024, 29 January (Evening Shift)

The total number of molecules with zero dipole moment among CH4, BF3, H2O, HF, NH3, CO2 and SO2 is .

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