Haloalkanes and Haloarenes
Previous year questions with solutions · 2025 – 2026
26 Questions
18 Papers covered
3.16% ↓13.9% Weightage in 2026
Year-wise statistics questions · papers · average per paper · weightage Year Questions Papers Avg / paper Weightage 2026 15 19 0.79 3.16% ↓13.9% 2025 11 12 0.92 3.67%
All 26 MCQ 20 Matching 4 Numerical 2
TopicAll Elimination Reactions of Haloalkanes Mechanism and Reactivity of SN1 and SN2 Nature of C–X Bond Nucleophilic and Electrophilic Substitution in Haloarenes Physical Properties of Haloalkanes and Haloarenes Preparation of Haloalkanes Preparation of Haloarenes Reaction of Haloalkanes and Haloarenes with Metals Stereochemistry of Nucleophilic Substitution Reactions Structure and Classification of Haloalkanes and Haloarenes YearAll 2026 2025
1
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
Both Statement I and Statement II are true Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true
JEE Main 2026 (Online) 8th April Evening Shift
2
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
Both Statement I and Statement II are true Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true
JEE Main 2026 (Online) 6th April Morning Shift
3
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below :
Both Statement I and Statement II are true Both Statement I and Statement II are false Statement I is true but Statement II is false Statement I is false but Statement II is true
JEE Main 2026 (Online) 2nd April Morning Shift
4
Correct statements regarding alkyl halides (R–X) among the following are : Choose the correct answer from the options given below :
A, B and C Only B and D Only A and E Only D and E Only
JEE Main 2026 (Online) 2nd April Evening Shift
5
Which of the following reactions is NOT correctly represented?
[figure] [figure] [figure] [figure]
JEE Main 2026 (Online) 28th January Evening Shift
6
Identify the correct statements : The presence of -NO2 group in benzene ring Choose the correct answer from the options given below :
A and D Only B and D Only C and A Only B and C Only
JEE Main 2026 (Online) 28th January Evening Shift
7
Given below are two statements : In the light of the above statements, choose the correct answer from the options given below
Statement I is false but Statement II is true Statement I is true but Statement II is false Both Statement I and Statement II are true Both Statement I and Statement II are false
JEE Main 2026 (Online) 24th January Morning Shift
8
As compared with chlorocyclohexane, which of the following statements correctly apply to chlorobenzene? Choose the correct answer from the options given below :
B, C and E Only A, C and E Only B, C and D Only A, D and E Only
JEE Main 2026 (Online) 22nd January Morning Shift
9
The correct order of the rate of reaction of the following reactants with nucleophile by SN1 mechanism is : (Given : Structures I and II are rigid) [figure]
I < II < III < IV II < I < III < IV III < I < II < IV IV < III < II < I
JEE Main 2026 (Online) 22nd January Morning Shift
10
The correct order of reactivity of CH3Br in methanol with the following nucleophiles is F-, I-, C2H5O- and C6H5O-
I- > C2H5O- > C6H5O- > F- I- > F- > C6H5O- > C2H5O- I- > C6H5O- > F- > C2H5O- I- > C2H5O- > F- > C6H5O-
JEE Main 2026 (Online) 22nd January Morning Shift
11
The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is : CH3Br + Nu- CH3Nu + Br-
ClO4- > CH3COO- > OH- > PhO- OH- > PhO- > CH3COO- > ClO4- CH3COO- > PhO- > OH- > ClO4- PhO- > OH- > CH3COO- > ClO4-
JEE Main 2026 (Online) 21st January Evening Shift
12
The correct order of reactivity of the following benzyl halides towards reaction with KCN is : [figure]
a > b > c > d b > a > d > c b > a > c > d a > b > d > c
JEE Main 2026 (Online) 21st January Evening Shift
13
The reactions which cannot be applied to prepare an alkene by elimination, are Choose the correct answer from the options given below:
B & E Only B, C & D Only A, C & D Only B & D Only
JEE Main 2025 (Online) 7th April Morning Shift
14
Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below :
Both Statement I and Statement II are incorrect Both Statement I and Statement II are correct Statement I is incorrect but Statement II is correct Statement I is correct but Statement II is incorrect
JEE Main 2025 (Online) 4th April Evening Shift
15
In the following series of reactions identify the major products A & B respectively : [figure]
[figure] [figure] [figure] [figure]
JEE Main 2025 (Online) 3rd April Evening Shift
16
In the following substitution reaction : [figure] Product 'P' formed is :
[figure] [figure] [figure] [figure]
JEE Main 2025 (Online) 29th January Morning Shift
17
The products A and B in the following reactions, respectively are A AgNO2 CH3-CH2-CH2-Br AgCN B
CH3-CH2-CH2-ONO, CH3-CH2-CH2-CN CH3-CH2-CH2-NO2, CH3-CH2-CH2-CN CH3-CH2-CH2-ONO, CH3-CH2-CH2-NC CH3-CH2-CH2-NO2, CH3-CH2-CH2-NC
JEE Main 2025 (Online) 28th January Morning Shift
18
Given below are two statements : In the light of the above statements, choose the most appropriate answer from the options given below
Both Statement I and Statement II are correct Statement I is incorrect but Statement II is correct Both Statement I and Statement II are incorrect Statement I is correct but Statement II is incorrect
JEE Main 2025 (Online) 28th January Morning Shift
19
The product B formed in the following reaction sequence is: [figure]
[figure] [figure] [figure] [figure]
JEE Main 2025 (Online) 28th January Evening Shift
20
The major product of the following reaction is: [figure]
6-Phenylhepta-3,5-diene 6-Phenylhepta-2,4-diene 2-Phenylhepta-2,4-diene 2-Phenylhepta-2,5-diene
JEE Main 2025 (Online) 28th January Evening Shift