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Aldehydes, Ketones and Carboxylic Acids

JEE Main 2024 (Online) 1st February Morning ShiftMatchingMedium📈 Topic in 12% papers+4−1
Ques. 1JEE Main 2024, 1 February (Morning Shift)

Match List - I with List - II. Choose the correct answer from the options given below :

  1. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
  2. (A)-(IV), (B)-(II), (C)-(III), (D)-(I)
  3. (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
  4. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Answer

(3) (A)-(IV), (B)-(II), (C)-(I), (D)-(III)

Solution

(A): ester → aldehyde (partial reduction, stops at –CHO) ⇒ DIBAL-H, H2O ⇒ (A) is (IV)

(B): C=O → CH2 (Clemmensen reduction) ⇒ Zn(Hg) and conc. HCl ⇒ (B) is (II)

(C): –CHO + CH3MgBr, then H2O ⇒ 2° alcohol with one extra C ⇒ (C) is (I)

(D): only the keto C=O → CH(OH); ∵ NaBH4 does not reduce the ester ⇒ (D) is (III)

∴ (A)-(IV), (B)-(II), (C)-(I), (D)-(III)

Answer: (3)

Keep practising — Aldehydes, Ketones and Carboxylic Acids

Ques. 2JEE Main 2024, 1 February (Evening Shift)

[figure] Acid D formed in above reaction is :

  1. Malonic acid
  2. Oxalic acid
  3. Succinic acid
  4. Gluconic acid
Ques. 3JEE Main 2024, 31 January (Morning Shift)

The product of the following reaction is P. [figure] The number of hydroxyl groups present in the product P is .

Ques. 4JEE Main 2024, 31 January (Evening Shift)

Identify major product 'P' formed in the following reaction. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 5JEE Main 2024, 31 January (Evening Shift)

Identify the name reaction. [figure]

  1. Stephen Reaction
  2. Etard Reaction
  3. Gattermann - Koch Reaction
  4. Rosenmund Reduction
Ques. 6JEE Main 2024, 30 January (Morning Shift)

[figure] This reduction reaction is known as:

  1. Wolff-Kishner reduction
  2. Etard reduction
  3. Stephen reduction
  4. Rosenmund reduction
Ques. 7JEE Main 2024, 30 January (Morning Shift)

In the given reactions, identify the reagent A and reagent B. [figure]

  1. A - CrO3 B - CrO3
  2. A - CrO3 B - CrO2Cl2
  3. A - CrO2Cl2 B - CrO3
  4. A - CrO2Cl2 B - CrO2Cl2
Ques. 8JEE Main 2024, 30 January (Morning Shift)

The compound formed by the reaction of ethanal with semicarbazide contains number of nitrogen atoms.

Ques. 9JEE Main 2024, 30 January (Evening Shift)

m-chlorobenzaldehyde on treatment with 50% KOH solution yields :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10JEE Main 2024, 29 January (Morning Shift)

The final product A formed in the following multistep reaction sequence is [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 11JEE Main 2024, 29 January (Morning Shift)

From the compounds given below, number of compounds which give positive Fehling's test is . Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4-nitrobenzaldehyde, cyclohexane carbaldehyde.

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