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Aldehydes, Ketones and Carboxylic Acids

JEE Main 2024 (Online) 1st February Evening ShiftMCQEasy📈 Topic in 14% papers+4−1
Ques. 1JEE Main 2024, 1 February (Evening Shift)

[figure] Acid D formed in above reaction is :

  1. Malonic acid
  2. Oxalic acid
  3. Succinic acid
  4. Gluconic acid

Answer

(3) Succinic acid

Solution

C2H5Br alc. KOH CH2=CH2 (A) ∵ dehydrohalogenation

Br2/CCl4 BrCH2-CH2Br (B) ∵ addition of Br2

KCN (excess) NC-CH2-CH2-CN (C) ∵ both Br replaced by CN

H3O+ (excess) HOOC-CH2-CH2-COOH (D) ∵ each –CN → –COOH

∴ D = butanedioic acid = succinic acid

Answer: (3)

Keep practising — Aldehydes, Ketones and Carboxylic Acids

Ques. 2JEE Main 2024, 31 January (Morning Shift)

The product of the following reaction is P. [figure] The number of hydroxyl groups present in the product P is .

Ques. 3JEE Main 2024, 31 January (Evening Shift)

Identify major product 'P' formed in the following reaction. [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 4JEE Main 2024, 31 January (Evening Shift)

Identify the name reaction. [figure]

  1. Stephen Reaction
  2. Etard Reaction
  3. Gattermann - Koch Reaction
  4. Rosenmund Reduction
Ques. 5JEE Main 2024, 30 January (Morning Shift)

[figure] This reduction reaction is known as:

  1. Wolff-Kishner reduction
  2. Etard reduction
  3. Stephen reduction
  4. Rosenmund reduction
Ques. 6JEE Main 2024, 30 January (Morning Shift)

In the given reactions, identify the reagent A and reagent B. [figure]

  1. A - CrO3 B - CrO3
  2. A - CrO3 B - CrO2Cl2
  3. A - CrO2Cl2 B - CrO3
  4. A - CrO2Cl2 B - CrO2Cl2
Ques. 7JEE Main 2024, 30 January (Morning Shift)

The compound formed by the reaction of ethanal with semicarbazide contains number of nitrogen atoms.

Ques. 8JEE Main 2024, 30 January (Evening Shift)

m-chlorobenzaldehyde on treatment with 50% KOH solution yields :

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 9JEE Main 2024, 29 January (Morning Shift)

The final product A formed in the following multistep reaction sequence is [figure]

  1. [figure]
  2. [figure]
  3. [figure]
  4. [figure]
Ques. 10JEE Main 2024, 29 January (Morning Shift)

From the compounds given below, number of compounds which give positive Fehling's test is . Benzaldehyde, Acetaldehyde, Acetone, Acetophenone, Methanal, 4-nitrobenzaldehyde, cyclohexane carbaldehyde.

Ques. 11JEE Main 2024, 29 January (Evening Shift)

Identify the reagents used for the following conversion [figure]

  1. A = LiAlH4, B = NaOH(aq), C = NH2-NH2/KOH, ethylene glycol
  2. A = DIBAL-H, B = NaOH(aq), C = NH2-NH2/KOH, ethylene glycol
  3. A = LiAlH4, B = NaOH(alc), C = Zn/HCl
  4. A = DIBAL-H, B = NaOH(alc), C = Zn/HCl

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