Principles Related to Practical Chemistry · Question 39

A mixture of 1 g each of chlorobenzene, aniline, and benzoic acid is dissolved in 50 mL ethyl acetate and placed in a separating funnel. 5 M NaOH (30 mL) was added in the same funnel. The funnel was shaken vigorously and then kept aside. The ethyl acetate layer in the funnel contains :

1. chlorobenzene and aniline
2. benzoic acid and aniline
3. benzoic acid
4. benzoic acid and chlorobenzene

In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas (N2) at 300 K temperature and 715 mm Hg pressure. The percentage composition of 'N' in the organic compound is % (Nearest integer) (Aqueous tension at 300 K = 15 mm Hg)

In Dumas' method for estimation of nitrogen 1 g of an organic compound gave 150 mL of nitrogen collected at 300 K temperature and 900 mm Hg pressure. The percentage composition of nitrogen in the compound is % (nearest integer) (Aqueous tension at 300 K = 15 mm Hg)

Match List-I with List-II Choose the correct answer from the options given below :

1. (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
2. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
3. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
4. (A)-(II), (B)-(I), (C)-(IV), (D)-(III)

During estimation of nitrogen by Dumas' method of compound X (0.42 g) [figure] mL of N2 gas will be liberated at STP. (nearest integer) (Given molar mass in g mol-1 : C : 12, H : 1, N : 14)

0.5 g of an organic compound on combustion gave 1.46 g of CO2 and 0.9 g of H2O. The percentage of carbon in the compound is . (Nearest integer) [Given : Molar mass (in g mol-1) C : 12, H : 1, O : 16]

Compounds that should not be used as primary standards in titrimetric analysis are : Choose the most appropriate answer from the options given below:

1. C, D and E Only
2. B and D Only
3. D and E Only
4. A, C and D Only

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at 300 K = 15 mm Hg)

1. 15.71\%
2. 17.46\%
3. 7.85\%
4. 20.95\%

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

1. A, D and E only
2. A, B and C only
3. B, D and E only
4. C, D and E only

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

1. 20.87
2. 12.57
3. 1.257
4. 18.67