Principles Related to Practical Chemistry · Question 41

In Dumas' method for estimation of nitrogen 1 g of an organic compound gave 150 mL of nitrogen collected at 300 K temperature and 900 mm Hg pressure. The percentage composition of nitrogen in the compound is % (nearest integer) (Aqueous tension at 300 K = 15 mm Hg)

Match List-I with List-II Choose the correct answer from the options given below :

1. (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
2. (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
3. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
4. (A)-(II), (B)-(I), (C)-(IV), (D)-(III)

During estimation of nitrogen by Dumas' method of compound X (0.42 g) [figure] mL of N2 gas will be liberated at STP. (nearest integer) (Given molar mass in g mol-1 : C : 12, H : 1, N : 14)

0.5 g of an organic compound on combustion gave 1.46 g of CO2 and 0.9 g of H2O. The percentage of carbon in the compound is . (Nearest integer) [Given : Molar mass (in g mol-1) C : 12, H : 1, O : 16]

Compounds that should not be used as primary standards in titrimetric analysis are : Choose the most appropriate answer from the options given below:

1. C, D and E Only
2. B and D Only
3. D and E Only
4. A, C and D Only

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at 300 K = 15 mm Hg)

1. 15.71\%
2. 17.46\%
3. 7.85\%
4. 20.95\%

Choose the correct tests with respective observations. Choose the correct answer from the options given below :

1. A, D and E only
2. A, B and C only
3. B, D and E only
4. C, D and E only

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at 300 K = 15 mm Hg) is %.

1. 20.87
2. 12.57
3. 1.257
4. 18.67

Formation of Na4[Fe(CN)5NOS], a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of:

1. Sulphide ion
2. Sulphite ion
3. Sulphate ion
4. Sodium ion

Match List-I with List-II. Choose the correct answer from the options given below:

1. (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
2. (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
4. (A)-(II), (B)-(III), (C)-(IV), (D)-(I)